Unusual behavior of bimetallic nanoparticles in catalytic processes of hydrogenation and selective oxidation

摘要

Recent results obtained in studying mono- and bimetallic catalysts for selective hydrogenation of unsaturated carbonyl compounds, even unsaturated ones, acetylenic and nitro compounds as well as CO and bio-available alcohols oxidation are reviewed from the standpoint of the strong interaction between the metal nanoparticles, on the one hand, and two metals in the composition of bimetallic nanoparticles, on the other hand. Such interactions were demonstrated to result in partial positive or negative charging of metal nanoparticles, which, in turn, changes their adsorption and catalytic properties, especially with respect to the reactions involving hydrogen. Among the systems studied, Au-Pt, Au-Pd, Au-Cu, Au-Fe, Pt-WOx, Fe-Pd, Fe-Pt, Fe-Cu nanoparticles prepared by the redox procedure are considered to be most perspective in diverse catalytic applications because of the proper combination of the particle size and the electronic state of the metals.