A calorimetric study of the process of formation of a supramolecular high-density polyethylene structure in mixtures with different oxides after plastic deformation under high pressure

摘要

Mixtures of ultrahigh-molecular-weight polyethylene with 95 wt % oxides of different elements were subjected to plastic deformation under the pressure of 1 GPa at a high pressure device of the Bridgman anvil type and thermal effects were studied using the DSC technique. Thermograms contained exothermic peaks with a maximum at 50-90A degrees C related to cold crystallization of the polymer. The process of polymer fusion was described by two peaks with the maximums at T (1) = 125-128A degrees C and T (2) = 136-139A degrees C. The low-temperature peak was related to fusion of a structure with high amounts of defects formed on the oxide surface.