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Synthesis and Characterization of Carbon Steel Corrosion Inhibitors Based on 4,5,6,7-tetrahydrobenzo[b]thiophene Scaffold

机译:基于4,5,6,7-四氢苯并[B]噻吩支架的碳钢腐蚀抑制剂的合成与表征

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摘要

Three novel inhibitors based on 4,5,6,7-tetrahydrobenzo[b]thiophene scaffold were synthesized and characterized. The inhibitive action of the synthesized inhibitors toward carbon steel acid corrosion was investigated using weight loss and polarization techniques. It was found that the three compounds act as good corrosion inhibitor for carbon steel in the acidic medium. The inhibition efficiency was found to increase with increasing concentration and decreased with increasing temperature. The adsorption of inhibitors molecules on the carbon steel surface follows Langmuir adsorption isotherm. The correlation between the inhibitors structures and their corrosion inhibition action was studied by quantum chemical calculations.
机译:合成并表征了基于4,5,6,7-四氢苯并噻吩的三种新型抑制剂[B]噻吩支架。 使用减肥和偏振技术研究了合成抑制剂对碳钢酸腐蚀的抑制作用。 发现三种化合物在酸性介质中发挥碳钢的良好腐蚀剂。 发现抑制效率随着浓度的增加而增加,随着温度的增加而降低。 抑制剂分子对碳钢表面的吸附遵循Langmuir吸附等温线。 通过量子化学计算研究了抑制剂结构与其腐蚀抑制作用之间的相关性。

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