Fabrication and Characterization of a Novel Underground Mining Emulsion Explosive Containing Thickening Microcapsules

Tao Chen; Cheng Yang‐Fan; Fang Hua; Yao Yu‐Le; Wang Yu‐Xiang; Ma Hong‐Hao; Shen Zhao‐Wu; Chen Yuan

摘要

Abstract > In order to solve the href="http://dict.cnki.net/dict_result.aspx?searchword=%e6%8e%89%e8%90%bd&tjType=sentence&style=&t=sloughing">sloughing</link> problem of explosives in upward blast holes, a novel underground mining emulsion explosive with thickening microcapsules was developed. The microcapsules in the emulsion explosive would be damaged by high‐speed shearing at the moment of entering the blast hole, releasing their internal thickening agents to the emulsion explosive in the blast holes. These thickening agents were evenly distributed with a linear network structure in the emulsion explosive to make it thickened in the hole. The microcapsules were spherical and could encapsulate the thickening agent effectively, and the viscosity of the emulsion matrix with 2?mass?% of them was close to that of the reference emulsion matrix at ca. 127.9?Pa?s. Experimental results of TG‐DSC and detonation performance showed that the novel underground mining emulsion explosive had a good thermal stability and its detonation velocity was 5133?m?s ?1 and still up to 4618?m?s ?1 after storing at the temperature of ?20?°C for 12?h. The novel underground mining emulsion explosive with thickening microcapsules not only achieved the goal of thickening in the blast holes, but also had excellent detonation performance and low‐temperature resistance capability. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 为了解决这个问题 href =“http://dict.cnki.net/dict_result.aspx?searchword=%e6%8E%89%E8%90%Bd＆骤数;tjtype=sentence & ;;style= & ;t=sloughing”> sloughing </链接> 开发了一种具有增稠微胶囊的新型地下采矿乳液的爆炸物问题。乳液炸药中的微胶囊将在进入喷砂孔时通过高速剪切损坏，将它们的内部增稠剂释放到喷射孔中的乳液中。这些增稠剂在乳液中的线性网络结构均匀分布，使其在孔中加厚。微胶囊是球形的，可以有效地包封增稠剂，并且乳液基质的粘度与2μm质量的粘度接近在Ca的参考乳液基质的粘度。 127.9？pa？s。 TG-DSC和爆炸性能的实验结果表明，新型地下采矿乳液爆炸性具有良好的热稳定性，其爆轰速度为5133ΩΩ·s ？1 </ sup> 并且仍然高达4618？？1 </ sup> 在Δ2℃的温度下储存12.℃后。该新型地下采矿乳液爆炸具有增厚微胶囊，不仅达到了鼓胀中加厚的目的，而且还具有出色的爆轰性能和低温阻力能力。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2020年第6期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tao Chen&option=202" target="_blank" rel="nofollow">Tao Chen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cheng Yang‐Fan&option=202" target="_blank" rel="nofollow">Cheng Yang‐Fan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fang Hua&option=202" target="_blank" rel="nofollow">Fang Hua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yao Yu‐Le&option=202" target="_blank" rel="nofollow">Yao Yu‐Le;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Yu‐Xiang&option=202" target="_blank" rel="nofollow">Wang Yu‐Xiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ma Hong‐Hao&option=202" target="_blank" rel="nofollow">Ma Hong‐Hao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shen Zhao‐Wu&option=202" target="_blank" rel="nofollow">Shen Zhao‐Wu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Yuan&option=202" target="_blank" rel="nofollow">Chen Yuan;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal MinesAnhui University of Science and TechnologyHuainan 232001 PR China;</p> <p>State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal MinesAnhui University of Science and TechnologyHuainan 232001 PR China;</p> <p>State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal MinesAnhui University of Science and TechnologyHuainan 232001 PR China;</p> <p>State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal MinesAnhui University of Science and TechnologyHuainan 232001 PR China;</p> <p>State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal MinesAnhui University of Science and TechnologyHuainan 232001 PR China;</p> <p>CAS Key Laboratory of Mechanical Behavior and Design of MaterialsUniversity of Science and Technology of ChinaHefei 230027 China;</p> <p>CAS Key Laboratory of Mechanical Behavior and Design of MaterialsUniversity of Science and Technology of ChinaHefei 230027 China;</p> <p>The 38th Research Institute of China Electronics Technology Group CorporationHefei 230088 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Upward hole&option=203" rel="nofollow">Upward hole;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Emulsion explosive&option=203" rel="nofollow">Emulsion explosive;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Underground mine&option=203" rel="nofollow">Underground mine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Microcapsule&option=203" rel="nofollow">Microcapsule;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thickening agent&option=203" rel="nofollow">Thickening agent;</a> </p> <div class="translation"> 机译：向上孔;乳液爆炸;地下矿井;微胶囊;增稠剂; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" 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Smith </a> <span>1959</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有核爆炸的地下采矿</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_material-science_thesis/0201264404842.html">无皂种子乳液聚合制备新型增稠剂</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨润苗1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨润苗1</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘玉海1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘玉海1</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邓瑶瑶1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邓瑶瑶1</a> <span> <a href="/journal-cn-38884/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 材料科学 </a> </span> <span> . 2013</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_anhui-chemical-industry_thesis/0201252001141.html">新型反相乳液聚合体系用于合成增稠剂</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴志超&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 吴志超</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=栾天平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,栾天平</a> <span> <a href="/journal-cn-9037/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 安徽化工 </a> </span> <span> . 1998</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-research_thesis/0201235530499.html">聚丙烯酸增稠剂的反相乳液聚合及其增稠性能</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=叶高勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 叶高勇</a> <span> <a href="/journal-cn-12031/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学研究 </a> </span> <span> . 2004</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-research-application_thesis/0201235606386.html">增稠剂的反相乳液聚合及增稠性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵振河&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵振河</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张高奇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张高奇</a> <span> <a href="/journal-cn-12032/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学研究与应用 </a> </span> <span> . 2002</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_polyurethane-industry_thesis/0201247656266.html">新型水性聚氨酯缔合型增稠剂的制备与表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蔡进勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 蔡进勇</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘志林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘志林</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=唐成&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,唐成</a> <span> <a href="/journal-cn-9169/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 聚氨酯工业 </a> </span> <span> . 2014</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-12198_thesis/02022582469.html">基于原位再制造自修复微胶囊的制备与表征</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ZHAO Yang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . ZHAO Yang</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵阳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵阳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ZHANG Wei&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,ZHANG Wei</a> <span> <a href="/conference-cn-12198/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第八届全国表面工程大会暨第三届青年表面工程学术论坛 </a> <span> <span> . 2010</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031379364.html">苯丙乳液/碱溶性丙烯酸系增稠剂的制备及其性能表征</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘永祥&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘永祥</a> <span> . 2006</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120104459948.html">含有亲水增稠化合物和增稠共聚物的乳液以及含有所述乳液的组合物及其用途</a> <b>[P]</b> . <span> 中国专利： CN1249926A </span> <span> . 2000-04-12</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104448546.html">含有亲水增稠化合物和多糖烷基醚的乳液以及含有所述乳液的组合物及其用途</a> <b>[P]</b> . <span> 中国专利： CN1249168A </span> <span> . 2000-04-05</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130420292682.html">AN EMULSION EXPLOSIVE AND CORD SYSTEM AND EMULSION EXPLOSIVE CARTRIDGES MADE THEREFROM, SUITABLE FOR USE IN BG METHOD IN UNDERGROUND COAL MINES</a> <b>[P]</b> . <span> 外国专利：  IN257679B </span> <span> . 2013-11-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由其制得的乳化炸药和帘线系统及乳化炸药，适用于地下煤矿的BG法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130422988324.html">surface or underground supply system for delivering emulsion explosive compositions into a probe bore, and method for providing an emulsion explosive composition into a probe bore.</a> <b>[P]</b> . <span> 外国专利：  BR0100597B1 </span> <span> . 2012-08-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于将乳化炸药组合物输送到探针孔中的地面或地下供应系统，以及用于将乳化炸药组合物提供到探针孔中的方法。 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130449112778.html">Supply system for the supply of surface or underground explosive compositions in emulsion into a hole of the probe, and.Process for the delivery of a composition in emulsion explosive into a borehole probe.</a> <b>[P]</b> . <span> 外国专利：  BR0100597A </span> <span> . 2001-10-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：供应系统，用于将乳化炸药中的表面或地下炸药组合物供应到探针的孔中，以及将乳化炸药中的组合物输送到井眼探针中的方法。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704024626680','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p 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