Fabrication of Ultra‐Fine TATB/HMX Cocrystal Using a Compound Solvent

Hou Conghua; Zhang Yuanping; Chen Yunge; Jia Xinlei; Zhang Shimin; Tan Yingxin

摘要

Abstract > A novel energetic cocrystal predicted to exhibit greater power and lower sensitivity, consisting of 1,3,5‐triamino‐2,4,6‐trinitrobenzene (TATB) and cyclotetramethylenetetranitramine (HMX) is presented. The TATB/HMX cocrystals were prepared using a compound solvent of [Emim]Ac and DMSO at 80?°C by recrystallization. Structural characterizations and thermal properties of the raw materials and cocrystals were systematically investigated by scanning electron microscopy (SEM), X‐ray diffraction, fourier‐transform infrared spectroscopy, fourier transform raman spectroscopy and differential scanning calorimetry. The SEM results indicated that microparticles are hexagonal in shape and ～2?μm in size. The formation of cocrystals originates from the N?H???O hydrogen bonding between ‐NO <sub>2</sub> (HMX) and ‐NH <sub>2</sub> (TATB). Naturally, compared to raw HMX, the impact sensitivity of the cocrystals is reduced. The EXPLO5 program showed TATB/HMX with desirable detonation performance. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> > 提出了一种新的精力充沛的CoCrystal，其具有较大的功率和更低的灵敏度，由1,3,5- Triamino-2,4,6-三硝基苯（TATB）和环氨酸四甲基四丁腈（HMX）组成。通过再结晶，使用80℃的化合物溶剂和DMSO的化合物制备TATB / HMX聚晶。通过扫描电子显微镜（SEM），X射线衍射，傅里叶变换红外光谱，傅里叶变换拉曼光谱和差示扫描量热法，系统地研究了原料和烯库的结构表征和热性质。 SEM结果表明，微粒是六边形的形状，〜2？μm的尺寸。聚晶的形成来自n？h ??? o氢键 - 之间的氢键 <sub> 2 </ sub> （HMX）和-NH <sub> 2 </ sub> （TATB）。当然，与原料HMX相比，COCrystals的冲击敏感性降低。 Explo5程序显示TATB / HMX，具有可取的爆轰性能。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2018年第9期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hou Conghua&option=202" target="_blank" rel="nofollow">Hou Conghua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Yuanping&option=202" target="_blank" rel="nofollow">Zhang Yuanping;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Yunge&option=202" target="_blank" rel="nofollow">Chen Yunge;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jia Xinlei&option=202" target="_blank" rel="nofollow">Jia Xinlei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Shimin&option=202" target="_blank" rel="nofollow">Zhang Shimin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tan Yingxin&option=202" target="_blank" rel="nofollow">Tan Yingxin;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Environment and Safety EngineeringNorth University of ChinaTaiyuan 030051 China;</p> <p>School of Environment and Safety EngineeringNorth University of ChinaTaiyuan 030051 China;</p> <p>School of Environment and Safety EngineeringNorth University of ChinaTaiyuan 030051 China;</p> <p>School of Environment and Safety EngineeringNorth University of ChinaTaiyuan 030051 China;</p> <p>School of Environment and Safety EngineeringNorth University of ChinaTaiyuan 030051 China;</p> <p>School of Environment and Safety EngineeringNorth University of ChinaTaiyuan 030051 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=TATB/HMX cocrystal&option=203" rel="nofollow">TATB/HMX cocrystal;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=EmimAc/DMSO compound solvent&option=203" rel="nofollow">EmimAc/DMSO compound solvent;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ultra-fine&option=203" rel="nofollow">ultra-fine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=performance&option=203" rel="nofollow">performance;</a> </p> <div class="translation"> 机译：TATB / HMX COCRYSTAL;[emim] AC / DMSO复合溶剂;超细;性能; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024626545.html">Fabrication of Ultra‐Fine TATB/HMX Cocrystal Using a Compound Solvent</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hou 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class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313835038.html">超细TATB的制备及TATB基传爆药配方设计初探</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴永炎&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 吴永炎</a> <span> . 2013</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120107909743.html">一种超细功能纤维及制备方法、使用超细功能纤维制备的超柔软功能毛巾及方法</a> <b>[P]</b> . <span> 中国专利： CN105442088A </span> <span> . 2016-03-30</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104126442.html">一种溶剂热处理辅助制备超细硼化锆粉体的方法</a> <b>[P]</b> . <span> 中国专利： CN111573688A </span> <span> . 2020-08-25</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130461604267.html">Arraying process of ultra-small objects and fabrication process of ultra-fine structure by using the arraying process</a> <b>[P]</b> . <span> 外国专利：  EP0529775A1 </span> <span> . 1993-03-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：超小型物体的排列工艺和利用该排列工艺制造超细结构的工艺 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130499916440.html">METHOD FOR PRODUCING ULTRA-FINE BUBBLE-CONTAINING LIQUID, ULTRA-FINE BUBBLE-CONTAINING LIQUID, METHOD FOR UTILIZING ULTRA-FINE BUBBLES, AND DEVICE FOR UTILIZING ULTRA-FINE BUBBLES</a> <b>[P]</b> . <span> 外国专利：  WO2021085629A1 </span> <span> . 2021-05-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制备含有超细气泡液，含有超细气泡液体的方法，用于利用超细气泡的方法，以及利用超细气泡的装置 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130499987663.html">Method for producing ultra fine bubble containing liquid, ultra fine bubble containing liquid, method of utilizing ultra fine bubble, and utilization apparatus of ultra fine bubble</a> <b>[P]</b> . <span> 外国专利：  JP2021074713A </span> <span> . 2021-05-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含有液体，超细泡液，利用超细泡沫的方法的超细泡沫，利用装置的制造方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704024626545','4',7,2,1,'',this,24)" class="delivery" prompt="010401" 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