Preparation of Ta(Ph)‐Fe/AP Composite Microspheres by Ultrasonic Spray Drying and Characterization of Their Catalytic Properties

Song Naimeng; Yang Li; Liu Pingan

摘要

Abstract >In this study, the ultrasonic spray drying technology was applied to prepare composite microspheres of catalyst (Ta?Fe, Ph?Fe) and AP. The surface morphology of the two composite microspheres was characterized by scanning electron microscopy (SEM). Their particle size distribution characteristics were tested by a nano laser particle size analyzer. The results showed that the spray drying technology can uniformly compound the AP and the catalyst into spherical particles. The thermal decomposition process of Ta(Ph)‐Fe/AP composite microspheres were tested by differential scanning calorimetry (DSC). The DSC data demonstrated that Ta(Ph)‐Fe/AP composite microsphere had a very good catalytic effect and significantly promoted the thermal decomposition process of AP. In addition, the catalytic mechanism was discussed by calculating the change in activation energy. Compared with the raw AP, the activation energies of the Ta?Fe/AP and Ph?Fe/AP composite microspheres were reduced by 18.5?kJ/mol and 28.1?kJ/mol, respectively. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 在本研究中，应用超声波喷雾干燥技术，制备催化剂的复合微球（Ta？Fe，pH？Fe）和AP。通过扫描电子显微镜（SEM）表征两种复合微球的表面形态。它们的粒度分布特性由纳米激光粒度分析仪测试。结果表明，喷雾干燥技术可以将AP和催化剂均匀化合物成球形颗粒。通过差示扫描量热法（DSC）测试TA（pH）-Fe / AP复合微球的热分解过程。 DSC数据证明TA（pH）-Fe / AP复合微球具有非常好的催化作用，并显着促进了AP的热分解过程。此外，通过计算活化能量的变化来讨论催化机制。与原始AP相比，TAαF/ AP和pHαF/ AP复合微球的激活能量分别减少18.5μl≤kJ/ mol和28.1 kJ / mol。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2020年第3期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Naimeng&option=202" target="_blank" rel="nofollow">Song Naimeng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Li&option=202" target="_blank" rel="nofollow">Yang Li;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Pingan&option=202" target="_blank" rel="nofollow">Liu Pingan;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Aerospace and Civil EngineeringHarbin Engineering UniversityHarbin 100051 P. R. China;</p> <p>State Key Laboratory of Explosion Science and TechnologyBeijing Institute of TechnologyBeijing 100081 P. R. China;</p> <p>College of Aerospace and Civil EngineeringHarbin Engineering UniversityHarbin 100051 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=composite microspheres&option=203" rel="nofollow">composite microspheres;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ta(Ph)-Fe/AP&option=203" rel="nofollow">Ta(Ph)-Fe/AP;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ultrasonic spray drying&option=203" rel="nofollow">ultrasonic spray drying;</a> </p> <div class="translation"> 机译：复合微球;TA（pH）-FE / AP;超声波喷雾干燥; 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Fujii&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">E. Fujii,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=T. Hyodo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">T. Hyodo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=K. Matsuo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">K. Matsuo,</a> <a href="/conference-foreign-27110/" target="_blank" rel="nofollow" class="tuijian_authcolor">Chemical Sensors 10 and MEMS/NEMS 10 .</a> <span>2012</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过使用PMMA微球模板的超声喷雾热解法制备的多孔In_2O_3基粉末的NO_2传感特性：PMMA微球尺寸对其气敏特性的影响</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061729163.html">SILVER ZIRCONIUM PHOSPHATE - PREPARATION, CHARACTERIZATION AND CATALYTIC PROPERTIES OF SILVER SUPPORTED ON ZIRCONIUM PHOSPHATE</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CHENG, SOOFIN.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">CHENG, SOOFIN. </a> <span>1982</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：磷酸银锆-磷酸锆上负载银的制备，表征和催化性能</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040006190949.html">Preparation and properties of chitosan‐based microspheres by spray drying</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zeng‐liang Zhang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zeng‐liang Zhang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li‐jie Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li‐jie Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dan Sun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dan Sun,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：喷雾干燥制备壳聚糖基微球及其性能</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100061089617.html">Preparation of cross-linked chitosan microspheres by spray drying: Effect of cross-linking agent on the properties of spray dried microspheres</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=K. G. H. Desai&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">K. G. H. Desai,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=H. J. Park&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">H. J. Park </a> <span>2004</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：喷雾干燥制备交联壳聚糖微球：交联剂对喷雾干燥微球性能的影响</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-energetic-materials_thesis/0201277531281.html">喷雾干燥法制备亚微米鞣酸铁/硝胺炸药复合微球及其催化性能</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨利&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨利</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李泓润&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李泓润</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋乃孟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋乃孟</a> <span> <a href="/journal-cn-8325/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 含能材料 </a> </span> <span> . 2020</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-inorganic-chemistry_thesis/0201271609010.html">光催化剂Sm2FeSbO7的制备及光物理和光催化性能表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=栾景飞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 栾景飞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谭文成&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谭文成</a> <span> <a href="/journal-cn-15070/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 无机化学学报 </a> </span> <span> . 2018</span><span>,第011期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201294321744.html">Fe203中的晶格氧用于甲烷在熔融盐中的催化燃烧(Ⅰ)催化剂的制备及性能表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何方&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 何方</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=戴永年&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,戴永年</a> <span> <a href="/journal-cn-57221/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国稀土学报 </a> </span> <span> . 2004</span><span>,第z1期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201294902696.html">Fe_2O_3/凹凸棒石Fenton催化剂的制备及性能表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张婷</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=冯辉霞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,冯辉霞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=苑晓微&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,苑晓微</a> <span> <a href="/journal-cn-57253/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 矿物岩石 </a> </span> <span> . 2011</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-central-south-university-science-technology_thesis/0201248344643.html">光Fenton反应催化剂Ce-Fe/Al2O3的等离子体制备及其性能表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张亚平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张亚平</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韦朝海&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,韦朝海</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姜涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,姜涛</a> <span> <a href="/journal-cn-4543/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中南大学学报（自然科学版） </a> </span> <span> . 2010</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-28559_thesis/020222034055.html">Fe<,2>O<,3>中的晶格氧用于甲烷在熔融盐中的催化燃烧(Ⅰ)催化剂的制备及性能表征</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何方&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 何方</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=戴永年&option=202" target="_blank" rel="nofollow" class="tuijian_auth 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