Effect of Decomposition of CuO Film on Ignition of Organic Explosives by a Laser Pulse

Khaneft Alexander; Mitrofanov Anatoly; Zverev Anton

摘要

Abstract > This work presents experimental results of the PETN ignition in a three‐layer system: glass – copper oxide ( <mat:math altimg="urn:x-wiley:07213115:media:prep201900047:prep201900047-math-0001" wiley:location="equation/prep201900047-math-0001.png"> <mat:mrow> <mat:mi mathvariant="normal">C</mat:mi> <mat:mi mathvariant="normal">u</mat:mi> <mat:mi mathvariant="normal">O</mat:mi> </mat:mrow> </mat:math> ) – explosive materials (EM) and results of numerical simulations of the ignition of PETN, RDX, HMX, and TATB with a <mat:math altimg="urn:x-wiley:07213115:media:prep201900047:prep201900047-math-0002" wiley:location="equation/prep201900047-math-0002.png"> <mat:mrow> <mat:mi mathvariant="normal">C</mat:mi> <mat:mi mathvariant="normal">u</mat:mi> <mat:mi mathvariant="normal">O</mat:mi> </mat:mrow> </mat:math> film heated by a YLS‐150 fiber laser with a pulse duration of <mat:math altimg="urn:x-wiley:07213115:media:prep201900047:prep201900047-math-0003" wiley:location="equation/prep201900047-math-0003.png"> <mat:mrow> <mat:mn>20</mat:mn> <mat:mspace width="1.69998pt"/> <mat:mspace width="1.69998pt"/> <mat:mi>ms</mat:mi> </mat:mrow> </mat:math> . In the numerical simulations, the endothermic reaction of decomposition of the <mat:math altimg="urn:x-wiley:07213115:media:prep201900047:prep201900047-math-0004" wiley:location="equation/prep201900047-math-0004.png"> <mat:mrow> <mat:mi mathvariant="normal">C</mat:mi> <mat:mi mathvariant="normal">u</mat:mi> <mat:mi mathvariant="normal">O</mat:mi> </mat:mrow> </mat:math> film and decomposition reaction of EM were taken into account. It has been established that the endothermic effect of the <mat:math altimg="urn:x-wiley:07213115:media:prep201900047:prep201900047-math-0005" wiley:location="equation/prep201900047-math-0005.png"> <mat:mrow> <mat:mi mathvariant="normal">C</mat:mi> <mat:mi mathvariant="normal">u</mat:mi> <mat:mi mathvariant="normal">O</mat:mi> </mat:mrow> </mat:math> decomposition reaction increases the dynamic ignition delay time of EM. The expression for an estimation of width of a reaction layer in EM at heating by a constant heat stream is obtained. Calculations have shown that the dynamic threshold of ignition of organic explosives by laser pulse in a three‐layer system (glass – <mat:math altimg="urn:x-wiley:07213115:media:prep201900047:prep201900047-math-0006" wiley:location="equation/prep201900047-math-0006.png"> <mat:mrow> <mat:mi mathvariant="normal">C</mat:mi> <mat:mi mathvariant="normal">u</mat:mi> <mat:mi mathvariant="normal">O</mat:mi> </mat:mrow> </mat:math> – EM) has a minimum for the thickness of the copper oxide film of <mat:math altimg="urn:x-wiley:07213115:media:prep201900047:prep201900047-math-0007" wiley:location="equation/prep201900047-math-0007.png"> <mat:mrow> <mat:mn>5</mat:mn> <mat:mspace width="1.69998pt"/> <mat:mspace width="1.69998pt"/> <mat:mrow> <mat:mi>μ</mat:mi> <mat:mrow/> </mat:mrow> <mat:mi mathvariant="normal">m</mat:mi> </mat:mrow> </mat:math> . The density of the critical ignition energy of an explosive laser pulse increases in the sequence of PETN, RDX, HMX, and TATB. The calculated </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 这项工作介绍了三层系统中佩特火点的实验结果：玻璃 - 氧化铜（ <MAT：MATH ALTIMG =“URN：X-Wiley：07213115：Media：Prep201900047：Prep201900047-Math-0001”Wiley：Location =“等式/ Prep201900047-Math-0001.png”> <MAT：MROW> <mat：mi mathvariant =“正常”> c </ mat：mi> <mat：mi mathvariant =“正常”> U </ mat：mi> <MAT：MI Mathvariant =“正常”> O </ MAT：MI> </ mat：MROW> </ mat：math> ） - 爆炸材料（EM）和佩特恩，RDX，HMX和TATB点火的数值模拟结果 <MAT：MATH ALTIMG =“URN：X-Wiley：07213115：Media：Prep201900047：Prep201900047-Math-0002”Wiley：Location =“等式/ Prep201900047-Math-0002.png”> <MAT：MROW> <mat：mi mathvariant =“正常”> c </ mat：mi> <mat：mi mathvariant =“正常”> U </ mat：mi> <MAT：MI Mathvariant =“正常”> O </ MAT：MI> </ mat：MROW> </ mat：math> 由YLS-150光纤激光加热的膜，脉冲持续时间 <MAT：MATH ALTIMG =“URN：X-Wiley：07213115：Media：Prep201900047：Prep201900047-Math-0003”Wiley：位置=“等式/ Prep201900047-Math-0003.png”> <MAT：MROW> <MAT：Mn> 20 </ mat：Mn <mat：mspace width =“1.69998pt”/> <mat：mspace width =“1.69998pt”/> <MAT：MI> MS </ MAT：MI> </ mat：MROW> </ mat：math> 。在数值模拟中，分解的附加反应 <MAT：MATH ALTIMG =“URN：X-Wiley：07213115：Media：Prep201900047：Prep201900047-Math-0004”Wiley：Location =“等式/ Prep201900047-Math-0004.png”> <MAT：MROW> <mat：mi mathvariant =“正常”> c </ mat：mi> <mat：mi mathvariant =“正常”> U </ mat：mi> <MAT：MI Mathvariant =“正常”> O </ MAT：MI> </ mat：MROW> </ mat：math> 考虑EM的薄膜和分解反应。已经确定了内热的效果 <MAT：MATH ALTIMG =“URN：X-Wiley：07213115：Media：Prep201900047：Prep201900047-Math-0005”Wiley：Location =“等式/ Prep201900047-Math-0005.png”> <MAT：MROW> <mat：mi mathvariant =“正常”> c </ mat：mi> <mat：mi mathvariant =“正常”> U </ mat：mi> <MAT：MI Mathvariant =“正常”> O </ MAT：MI> </ mat：MROW> </ mat：math> 分解反应增加了EM的动态点火延迟时间。得到通过恒定热流加热的EM中反应层宽度估计的表达。计算表明，通过三层系统中的激光脉冲通过激光脉冲点火的动态阈值（玻璃 - <MAT：MATH ALTIMG =“URN：X-Wiley：07213115：Media：Prep201900047：Prep201900047-Math-0006”Wiley：Location =“等式/ Prep201900047-Math-0006.png”> <MAT：MROW> <mat：mi mathvariant =“正常”> c </ mat：mi> <mat：mi mathvariant =“正常”> U </ mat：mi> <MAT：MI Mathvariant =“正常”> O </ MAT：MI> </ mat：MROW> </ mat：math> - EM）对于氧化铜膜的厚度有最小 <MAT：MATH ALTIMG =“URN：X-WIley：07213115：Media：Prep201900047：Prep201900047-Math-0007”Wiley：Location =“等式/ Prep201900047-Math-0007.png”> <MAT：MROW> <MAT：MN> 5 </ MAT：MN> <mat：mspace width =“1.69998pt”/> <mat：mspace width =“1.69998pt”/> <MAT：MROW> <MAT：MI>μ</ MAT：MI> <MAT：MROW /> </ mat：MROW> <mat：mi mathvariant =“正常”> m </ mat：mi> </ mat：MROW> </ mat：math> 。爆炸激光脉冲的临界点火能量的密度在PETN，RDX，HMX和TATB的序列中增加。计算出 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2019年第12期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Khaneft Alexander&option=202" target="_blank" rel="nofollow">Khaneft Alexander;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mitrofanov Anatoly&option=202" target="_blank" rel="nofollow">Mitrofanov Anatoly;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zverev Anton&option=202" target="_blank" rel="nofollow">Zverev Anton;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Kemerovo State UniversityKemerovo 650000 Russia;</p> <p>Kemerovo State UniversityKemerovo 650000 Russia;</p> <p>Kemerovo State UniversityKemerovo 650000 Russia;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=simulation&option=203" rel="nofollow">simulation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=laser ignition&option=203" rel="nofollow">laser ignition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=explosive&option=203" rel="nofollow">explosive;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=copper oxide&option=203" rel="nofollow">copper oxide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=PETN&option=203" rel="nofollow">PETN;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=RDX&option=203" rel="nofollow">RDX;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=HMX&option=203" rel="nofollow">HMX;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=TATB&option=203" rel="nofollow">TATB;</a> </p> <div class="translation"> 机译：模拟;激光点火;爆炸;氧化铜;佩特;RDX;HMX;TATB; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> 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D.,</a> <span>1993</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：脉冲激光沉积亚稳态Ca（1-x）sr（x）CuO2薄膜。</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-energetic-materials_thesis/0201227052423.html">多晶硅与Al/CuO复合薄膜集成的含能点火器件的点火性能</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李勇</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高泽志&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,高泽志</a> <span> <a href="/journal-cn-8325/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 含能材料 </a> </span> <span> . 2016</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_initiators-pyrotechnics_thesis/0201226956674.html">纳米Al-CuO/氧化石墨烯含能点火桥膜的制备与电爆性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李婷婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李婷婷</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李家宽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李家宽</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,胡艳</a> <span> <a href="/journal-cn-8322/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 火工品 </a> </span> <span> . 2018</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangdong-chemical-industry_thesis/0201246324509.html">Si-Bi2O3对Al-CuO铝热剂点火性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周建中&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周建中</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=田进&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,田进</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=薛国华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,薛国华</a> <span> <a href="/journal-cn-9122/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东化工 </a> </span> <span> . 2016</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-solid-rocket-technology_thesis/0201219359617.html">固体火箭发动机点火过程中点火具破膜过程的数值模拟</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=唐必顺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 唐必顺</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=封锋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,封锋</a> <span> <a href="/journal-cn-9899/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 固体火箭技术 </a> </span> <span> . 2013</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_motorcycle-technology_thesis/0201223051129.html">交流电子点火器的属性直流电子点火器的性能——记新型交流电子点火器“点火先锋”</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . </a> <span> <a href="/journal-cn-10091/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 摩托车技术 </a> </span> <span> . 2012</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-60733_thesis/020222786509.html">脉冲点火器多头同时点火和分别点火的对比研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Steven&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Steven</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grubby&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Grubby</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mendy&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Mendy</a> <span> <a href="/conference-cn-60733/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2018中国燃气具行业年会 </a> <span> <span> . 2018</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313016781.html">Al-CuO/氧化石墨烯含能点火桥膜的制备与性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李家宽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李家宽</a> <span> . 2016</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201097474.html">硅杯聚能Al/CuO复合薄膜点火桥和点火桥阵列</a> <b>[P]</b> . <span> 中国专利： CN102249830B </span> <span> . 2013.01.02</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061201106578.html">介电式Al/CuO复合薄膜含能电点火桥和点火桥阵列</a> <b>[P]</b> . <span> 中国专利： CN102260125B </span> <span> . 2013.01.30</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130401835910.html">Metal-organic pulsed laser deposition for stoichiometric complex oxide thin films</a> <b>[P]</b> . <span> 外国专利：  US10796907B2 </span> <span> . 2020-10-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：化学计量的复合氧化物薄膜的金属有机脉冲激光沉积 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130401595354.html">METAL-ORGANIC PULSED LASER DEPOSITION FOR STOICHIOMETRIC COMPLEX OXIDE THIN 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