Environment‐Friendly Formation of High Energetic Nano‐Al/Fe2O3 Bilayer by Aqueous Electrophoretic Deposition

Zhang Daixiong; Pei Rui; Peng Xiofei; Xiang Qing; Wang Xia

摘要

Abstract > In this study, nano‐Al/Fe <sub>2</sub> O <sub>3</sub> bilayer was successfully formed via aqueous electrophoretic deposition (EPD) route for the first time. For this formation, the first layer of nano‐Fe <sub>2</sub> O <sub>3</sub> was prepared by EPD using the bi‐additive of 0.015?mM HCl+10?mg?L ?1 PEI, and then the second layer of nano‐Al was immediately prepared by EPD using 5?mg?L ?1 PEI as additive. The electrophoretic nano‐Al/Fe <sub>2</sub> O <sub>3</sub> bilayer had high heat release of ～2800?J?g ?1 and exhibited good combustion performance. In comparison with the previous work realized by using organic‐solvent‐EPD, we believe this study can pave a new way for preparing the bilayers of nanothermites or metallic reactive materials by more cost‐effective and environment‐friendly aqueous EPD route. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 在本研究中，纳米Al / Fe <sub> 2 </ sub> O. <sub> 3 </ sub> 双层通过电泳沉积（EPD）首次成功地形成。对于这种形成，第一层纳米FE <sub> 2 </ sub> O. <sub> 3 </ sub> 通过EPD使用0.015ΩmmHCl + 10？MG？L的双添加剂制备？1 </ sup> PEI，然后通过EPD使用5？MG？L立即由EPD制备第二层纳米-A1 ？1 </ sup> pei作为添加剂。电泳纳米Al / Fe <sub> 2 </ sub> O. <sub> 3 </ sub> 双层的热释放〜2800？J？G ？1 </ sup> 并表现出良好的燃烧性能。与使用有机溶剂-EPD实现的以前的工作相比，我们认为这项研究可以通过更具成本效益和环保的含水环路途径制备纳米罐或金属反应材料的双层的新方法。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2019年第12期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Daixiong&option=202" target="_blank" rel="nofollow">Zhang Daixiong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pei Rui&option=202" target="_blank" rel="nofollow">Pei Rui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Peng Xiofei&option=202" target="_blank" rel="nofollow">Peng Xiofei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xiang Qing&option=202" target="_blank" rel="nofollow">Xiang Qing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xia&option=202" target="_blank" rel="nofollow">Wang Xia;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Environment and ResourcesChongqing Technology and Business UniversityChongqing 400067 P. R. China;</p> <p>School of Materials Science and EngineeringSouthwest Petroleum UniversityChengdu 610500 P. R. China;</p> <p>School of Materials Science and EngineeringSouthwest Petroleum UniversityChengdu 610500 P. R. China;</p> <p>Sichuan Fine Arts InstituteChongqing 401331 P. R. China;</p> <p>School of Materials Science and EngineeringSouthwest Petroleum UniversityChengdu 610500 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Al/Fe2O3&option=203" rel="nofollow">Al/Fe2O3;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bilayers&option=203" rel="nofollow">Bilayers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thick films&option=203" rel="nofollow">Thick films;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aqueous electrophoretic deposition&option=203" rel="nofollow">Aqueous electrophoretic deposition;</a> </p> <div class="translation"> 机译：Al / Fe2O3;双层;厚膜;水电泳沉积; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李志友&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李志友</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马莉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,马莉</a> <span> <a href="/journal-cn-7976/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 粉末冶金材料科学与工程 </a> </span> <span> . 2011</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-26669_thesis/020221680604.html">α-FeOOH为原料利用高能球磨制备α-Fe2O3纳米粒子</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王丽丽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王丽丽</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姜继森&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,姜继森</a> <span> <a href="/conference-cn-26669/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2005年上海市颗粒学会年会 </a> <span> <span> . 2005</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314741773.html">类环状Fe2O3微米环的形成机理及润湿性对Fe2O3纳米环形成的影响</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郭允锋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郭允锋</a> <span> . 2013</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120113773769.html">一种空心碳纳米球/Al/Fe2O3基纳米铝热剂的直写制备方法</a> <b>[P]</b> . <span> 中国专利： CN113770374A </span> <span> . 2021-12-10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061201496769.html">制备α-Fe2O3空心结构及α-Fe2O3/K1.33Mn8O16纳米线的方法</a> <b>[P]</b> . <span> 中国专利： CN103288139B </span> <span> . 2014.11.26</span> </div> </li> <li> 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