Analysis of a novel CuCl2 back contact process for improved stability in CdTe solar cells

Artegiani Elisa; Menossi Daniele; Shiel Huw; Dhanak Vin; Major Jonathan D.; Gasparotto Andrea; Sun Kai; Romeo Alessandro

摘要

Abstract > One of the crucial points in the production of CdTe solar cells is the insertion of copper in the back contact and in the absorber. As demonstrated by the top performing devices presented in literature: copper is necessary for high efficiency devices. However, despite this, copper was found to be a fast diffuser degrading the cell in the long term. Different approaches for limiting this effect have been widely presented from several laboratories, from the preparation of Cu <sub>x</sub> Te by the controlled evaporation of Cu and Te to the application of ZnTe, which incorporates Cu, blocking its diffusion in the bulk. We have developed a wet deposition method for inserting in the CdTe structure a quantity of copper equivalent to a 0.1‐nm‐thick Cu layer. We are able to reach similar efficiencies to the ones of devices with a standard 2‐nm‐thick evaporated copper layer, but with a dramatic improvement in performance stability. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > CDTE太阳能电池生产中的一个关键点是在后接触和吸收器中插入铜。正如文献中呈现的顶部执行设备所示：高效设备需要铜。然而，尽管如此，发现铜被发现是长期降解细胞的快速扩散器。限制这种效果的不同方法已被广泛从若干实验室中呈现，从铜的制备中呈现 <sub> x </ sub> 通过控制Cu和Te的受控蒸发到ZnTe的应用，该ZnTe包含Cu，阻挡其在体积中的扩散。我们开发了一种湿沉积方法，用于插入CDTE结构的铜等于0.1nm厚的Cu层。我们能够与标准的2nm厚的蒸发铜层的装置达到类似的效率，但具有显着提高性能稳定性。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29870/'>《Progress in photovoltaics》</a> <b style="margin: 0 2px;">|</b><span>2019年第8期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Artegiani Elisa&option=202" target="_blank" rel="nofollow">Artegiani Elisa;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Menossi Daniele&option=202" target="_blank" rel="nofollow">Menossi Daniele;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shiel Huw&option=202" target="_blank" rel="nofollow">Shiel Huw;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dhanak Vin&option=202" target="_blank" rel="nofollow">Dhanak Vin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Major Jonathan D.&option=202" target="_blank" rel="nofollow">Major Jonathan D.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gasparotto Andrea&option=202" target="_blank" rel="nofollow">Gasparotto Andrea;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Kai&option=202" target="_blank" rel="nofollow">Sun Kai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Romeo Alessandro&option=202" target="_blank" rel="nofollow">Romeo Alessandro;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>LAPS—Laboratory for Photovoltaics and Solid State Physics Department of Computer ScienceUniversity of VeronaCa' Vignal 1 Strada Le Grazie 15 37134 Verona Italy;</p> <p>LAPS—Laboratory for Photovoltaics and Solid State Physics Department of Computer ScienceUniversity of VeronaCa' Vignal 1 Strada Le Grazie 15 37134 Verona Italy;</p> <p>Stephenson Institute for Renewable Energy and Department of PhysicsUniversity of LiverpoolLiverpool L69 7ZF UK;</p> <p>Stephenson Institute for Renewable Energy and Department of PhysicsUniversity of LiverpoolLiverpool L69 7ZF UK;</p> <p>Stephenson Institute for Renewable Energy and Department of PhysicsUniversity of LiverpoolLiverpool L69 7ZF UK;</p> <p>Department of Physics and Astronomy “G. Galilei”University of PadovaVia F. Marzolo 8 35131 Padova Italy;</p> <p>Department of Materials Science and EngineeringUniversity of MichiganAnn Arbor MI USA;</p> <p>LAPS—Laboratory for Photovoltaics and Solid State Physics Department of Computer ScienceUniversity of VeronaCa' Vignal 1 Strada Le Grazie 15 37134 Verona Italy;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7667.html" title="通信系统（传输系统）">通信系统（传输系统）;</a><a href="https://www.zhangqiaokeyan.com/clc/1790.html" title="光电子技术、激光技术">光电子技术、激光技术;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=back contact&option=203" rel="nofollow">back contact;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CdTe&option=203" rel="nofollow">CdTe;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=copper&option=203" rel="nofollow">copper;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CuCl 2&option=203" rel="nofollow">CuCl 2;</a> </p> <div class="translation"> 机译：背部接触;CDTE;铜;CUCL 2; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" 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href="/academic-conference-cn_meeting-39488_thesis/020222410896.html">N型双面电池背面复合分析及改善技术研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵晨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵晨</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陶智华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陶智华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑飞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郑飞</a> <span> <a href="/conference-cn-39488/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十二届中国太阳级硅及光伏发电研讨会 </a> <span> <span> . 2016</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315097310.html">改善钙钛矿太阳能电池稳定性的电极材料与封装工艺研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=方少英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 方少英</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201843071.html">背面电极型太阳能电池单元、带有配线板的背面电极型太阳能电池单元、太阳能电池模块、带有配线板的背面电极型太阳能电池单元的制造方法及太阳能电池模块的制造方法</a> <b>[P]</b> . <span> 中国专利： CN103229307B </span> <span> . 2015.11.25</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120101936981.html">背面电极型太阳能电池单元、带有配线板的背面电极型太阳能电池单元、太阳能电池模块、带有配线板的背面电极型太阳能电池单元的制造方法及太阳能电池模块的制造方法</a> <b>[P]</b> . <span> 中国专利： CN103229307A </span> <span> . 2013-07-31</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130412890888.html">RAPID THERMAL PROCESSING OF BACK CONTACTS FOR CDTE SOLAR CELLS</a> <b>[P]</b> . <span> 外国专利：  US2015325718A1 </span> <span> . 2015-11-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：CDTE太阳电池后触点的快速热处理 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130403867104.html">CDS/CDTE REAR CONTACT SOLAR CELLS IMPROVED WITH CU/MO.</a> <b>[P]</b> . <span> 外国专利：  MX363660B </span> <span> . 2019-03-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：改进了CU / MO的CDS / CDTE后接触太阳能电池。 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130412080446.html">CDS/CDTE REAR CONTACT SOLAR CELLS IMPROVED WITH CU/MO.</a> <b>[P]</b> . <span> 外国专利：  MX2014007276A </span> <span> . 2015-12-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：改进了CU / MO的CDS / CDTE后接触太阳能电池。 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