Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

Shigeru Sasaki; Midori Murakami; Masaaki Yoshifuji

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Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

机译：具有两种吩噻嗪部分的空心三芳基膦的合成和氧化还原性能

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摘要

The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.

机译：合成了作为氧化还原位点的空中拥挤的三芳基膦含有两种吩噻嗪部分。膦酸环的循环伏安图表现出三步可逆氧化，与含有一根吩噻嗪部分的三芳膦膦的相比表明氧化还原过程中阳性电荷的分层化。

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来源
《Phosphorus, Sulfur, and Silicon and the Related Elements 》 |2019年第6期| 共5页
作者
Shigeru Sasaki; Midori Murakami; Masaaki Yoshifuji;
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作者单位

Department of Chemistry Graduate School of Science Tohoku University;

Department of Chemistry Graduate School of Science Tohoku University;

Department of Chemistry Graduate School of Science Tohoku University;

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原文格式 PDF
正文语种 eng
中图分类非金属元素及其化合物 ;
关键词
Phosphine; triarylphosphine; phenothiazine; cyclic voltammogram;

机译：膦;三芳基膦;吩噻嗪;循环伏安图;

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1. Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties [J] . Shigeru Sasaki, Midori Murakami, Masaaki Yoshifuji Phosphorus, Sulfur, and Silicon and the Related Elements . 2019 ,第4a6期

机译：具有两种吩噻嗪部分的空心三芳基膦的合成和氧化还原性能
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Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

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