Phase transitions in a metal-organic coordination polymer: [Zn-2(C8H4O4)(2)(C6H12N2)] with guest molecules. Thermal effects and molecular mobility

摘要

Thermal effects of a series of [Zn-2(C8H4O4)(2)(C6H12N2)] porous compound with the guest molecules located in the pores were studied using differential scanning calorimetry combined with solid-state H-1 nuclear magnetic resonance spectroscopy. The intercalation of the molecules was shown to produce various thermal anomalies and phase transitions, which were characterized and analyzed.