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alpha-Fe2O3 supported Bi2WO6 for photocatalytic degradation of gaseous benzene

机译:Alpha-Fe2O3支持的Bi2WO6用于光催化苯的光催化降解

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摘要

The Bi2WO6/alpha-Fe2O3 composite photocatalyst was synthesized by using goethite as a precursor through hydrothermal-calcination method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-Vis reflection spectrometer (DRS), X-ray photoelectron spectroscopy (XPS) and N-2 adsorption-desorption measurement (BET). These results indicated that the self-made composite photocatalysts had excellent catalytic performance of degradation of gaseous benzene. When benzene initial concentration at 50 mg/m(3), over the alpha-FeOOH/Bi2WO6 with molar mass of 0.8: 1, calcined at 350 degrees C for 2 h and the pH of precursor solution was 3, the benzene degradation rate reached 71.9% and the mineralization efficiency reached 67.7% after 220 min UV irradiation, respectively. The h(+) and O-center dot(2)- generated in the photocatalytic system should be played a pivotal role for the enhanced photodegradation performance of gaseous benzene. (C) 2017 Elsevier Masson SAS. All rights reserved.
机译:通过使用热热煅烧方法使用甲磺酸盐作为前体合成Bi2WO6 /α-Fe2O3复合光催化剂,并通过X射线衍射(XRD),扫描电子显微镜(SEM),UV-Vis反射光谱仪(DRS),X-光线光电子体光谱(XPS)和N-2吸附 - 解吸测量(BET)。这些结果表明,自制造的复合光催化剂具有优异的气态苯降解的催化性能。当苯初始浓度为50mg / m(3)时,通过摩尔质量为0.8:1的α-FeO​​OH / Bi2WO6,在350℃下煅烧2小时,前体溶液的pH为3,苯降解率达到220分钟辐照后,71.9%,矿化效率达到67.7%。在光催化系统中产生的H(+)和O中心点(2)应在增强气态苯的光降解性能下发挥枢转作用。 (c)2017年Elsevier Masson SAS。版权所有。

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