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Study of CO 2 and CH 4 Permeation Properties through Prepared and Characterized Blended Pebax-2533/PEG-200 Membranes

机译:通过制备和表征混合PeBAX-2533 / PEG-200膜,CO <下标> 2 和CH <下标> 4 渗透性能的研究

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This study demonstrates how incorporation of polyethylene glycol (PEG-200) into poly (ether- block -amide) (Pebax-2533) can improve the prepared membrane performance in separating CO~(2)from CH~(4). Additionally, the effect of various PEG-200 loadings on CH~(4)and CO~(2)permeability and CO~(2)/CH~(4)selectivity values was investigated. The prepared membranes were examined using Fourier transform infrared (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses. Permeation experiments of the gasses through the neat Pebax and the blended (Pebax-2533/PEG-200) membranes were carried out at a temperature of 25_(°)C and pressure range of 2 to 10 bar. The gas permeation experiments indicated that the performance of blended membranes is better than that of the neat membrane. As an example, CO~(2)permeability and ideal CO~(2)/CH~(4)selectivity values for the blended membrane with 40 wt.% of PEG-200 loading are 351.65 and 9.17 Barrer, while those values for the neat membrane are 187.54 and 7.28 Barrer, respectively.
机译:该研究表明将聚乙二醇(PEG-200)掺入聚(醚嵌段 - 酰胺)(PEBAX-2533)可以改善从CH〜(4)分离CO〜(2)中的制备的膜性能。另外,研究了各种PEG-200载荷对CH〜(4)和CO〜(2)渗透性和CO〜(2)/ CH〜(4)选择性值的影响。使用傅里叶变换红外(FTIR),X射线衍射(XRD)和扫描电子显微镜(SEM)分析来检查制备的膜。通过纯净Peax和混合(PeBax-2533 / PEG-200)膜的渗透实验在25_(°)C和2至10巴的压力范围内进行。气体渗透实验表明混合膜的性能优于整齐膜的性能。作为一个例子,CO〜(2)渗透率和理想的CO〜(2)/ CH〜(4)混合膜的选择性值,其中混合膜具有40重量%。PEG-200负载的%是351.65和9.17个禁迹,而那些值纯膜分别为187.54和7.28个禁迹。

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