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Sonochemical synthesis and characterization of silver tungstate nanostructures as visible-light-driven photocatalyst for waste-water treatment

机译:银钨纳米结构的多种化学合成与表征,作为废水处理的可见光光催化剂

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摘要

Highly active nanostructured silver tungstate for visible-light-driven photocatalysis is fabricated via an effortless and quick sonochemical pathway. Role of capping agent kind, concentration of tungsten source and time of sonication as efficacious variables has been explored for fabrication of silver tungstate through sonochemical pathway. The outcomes denoted successful fabrication of homogeneous silver tungstate nanoparticles with fine size in optimal circumstance (30 min of sonication, usage of SDBS and 0.01 mol of tungsten source). As-fabricated photocatalyst, the nanostructured silver tungstate has been identified with the aid of multiple techniques. The created silver tungstate micro/nanostructures employed to degrade diverse contaminants beneath visible light. Degradation yield of 94.23% for Acid red 14 and 96.31% for eriochrome cyanine R and 100% for Rhodamine B has been obtained with the help of the nanostructured silver tungstate (created in optimal circumstance) within 60 min. Further, nanostructured silver tungstate could completely destruct 2-naphthol within 15 min. No considerable decrement in performance was seeable within re-utilized experiments. The easy, effortless and quick fabrication of highly active nanostructured silver tungstate for visible-light-driven photocatalysis through sonochemical pathway may contribute efficient in environmental remediation.
机译:高活性纳米结构银钨酸盐通过毫不费力和快速的儿童化学途径制造可见光光催化剂。封装代理人的作用,作为有效变量的钨源和超声时间的浓度,用于通过儿童化学途径制作银钨酸盐。结果表明,在最佳情况下成功地制备均匀银钨酸盐纳米粒子(30分钟的超声处理,SDBS和0.01摩尔钨源)。借助多种技术已经鉴定了纳米结构银钨酸盐。所产生的银钨酸盐微/纳米结构用于降解可见光下方的不同污染物。在60分钟内的纳米结构银钨(在最佳情况下在最佳情况下在最佳情况下在最佳情况下在最佳情况下在最佳情况下在最佳情况下在最佳情况下在最佳情况下在最佳情况下在最佳情况下产生),获得了94.23%的降解产率为94.23%。此外,纳米结构银钨酸盐可以在15分钟内完全破坏2-萘酚。在重新利用实验中,性能下不可能减少。通过Sonochemical途径的可见光驱动的光催化的高活性纳米结构银钨酸酯容易,轻松,快速制造,可以有助于在环境修复中有效。

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