Kinetic Isotope H/D Effect in the Oxidation of Ethers of Linoleic Acid in Solutions

Tikhonov I. V.; Moskalenko I. V.; Pliss E. M.; Fomich M. A.; Bekish A. V.; Shmanai V. V.

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Kinetic Isotope H/D Effect in the Oxidation of Ethers of Linoleic Acid in Solutions

机译：动力学同位素H / D在溶液中亚油酸醚的氧化效应

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It is shown that the initiated oxidation of deuterated esters of linoleic acid proceeds as a radical chain process. The value of the kinetic isotope effect for hydrogen atom abstraction from the bisallyl group of linoleic acid esters is determined: 3.0 for tert-butyl peroxy and cumylperoxy radicals.

机译：结果表明，引发的亚油酸氘代酯的氧化作为自由基链过程。测定来自二碱基亚油酸酯的氢原子抽取的动力学同位素效应的值：3.0，用于过氧的叔丁基和枯氧基自由基。

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来源
《Russian journal of physical chemistry, B.》 |2017年第3期|共5页
作者
Tikhonov I. V.; Moskalenko I. V.; Pliss E. M.; Fomich M. A.; Bekish A. V.; Shmanai V. V.;
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作者单位

Demidov Yaroslavl Univ Yaroslavl 150000 Russia;

Demidov Yaroslavl Univ Yaroslavl 150000 Russia;

Demidov Yaroslavl Univ Yaroslavl 150000 Russia;

Natl Acad Sci Belarus Inst Phys Organ Chem Minsk 220072 Byelarus;

Belarusian State Univ Minsk 220030 Byelarus;

Natl Acad Sci Belarus Inst Phys Organ Chem Minsk 220072 Byelarus;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
kinetic isotope effect; oxidation; polyunsaturated fatty acids; hydrogen atom abstraction;

机译：动力学同位素效应;氧化;多不饱和脂肪酸;氢原子抽象;

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1. Kinetic Isotope H/D Effect in the Oxidation of Ethers of Linoleic Acid in Solutions [J] . Tikhonov I. V., Moskalenko I. V., Pliss E. M., Russian journal of physical chemistry, B. . 2017,第3期

机译：动力学同位素H / D在溶液中亚油酸醚的氧化效应
2. The enzymic and non-enzymic degradation of colneleic acid, an unsaturated fatty acid ether intermediate in the lipoxygenase pathway of linoleic acid oxidation in potato (Solanum tuberosum) tubers [J] . D. A. Wardale, J. A. Matthew, T. Galliard The biochemical journal . 1974,第1期

机译：马铃薯块茎亚油酸氧化脂氧合酶途径中的不饱和脂肪酸醚中间体-烯酸的酶促和非酶促降解
3. Kinetics of microbial hydrogenation of free linoleic acid to conjugated linoleic acids [J] . Xu H., Lee H.Y., Hwang B., Journal of applied microbiology . 2008,第6期

机译：游离亚油酸微生物加氢成共轭亚油酸的动力学
4. Kinetics of reanodization of porous anodic oxide films on aluminium formed in pore-forming solutions of various acids [C] . Alexander Stefanov Zahariev, Boriana Rangelova Tzaneva, Christian Assenov Girginov, International Scientific Conference Electronics . 2017

机译：在各种酸的成孔溶液中形成的铝上的多孔阳极氧化膜的再阳极氧化动力学
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. The enzymic and non-enzymic degradation of colneleic acid an unsaturated fatty acid ether intermediate in the lipoxygenase pathway of linoleic acid oxidation in potato (Solanum tuberosum) tubers [O] . T. Galliard, D. A. Wardale, J. A. Matthew 1974

机译：马铃薯（Solanum tuberosum）块茎亚油酸氧化脂氧合酶途径中的不饱和脂肪酸醚中间体-烯乙酸的酶促和非酶促降解
7. The enzymic and non-enzymic degradation of colneleic acid, an unsaturated fatty acid ether intermediate in the lipoxygenase pathway of linoleic acid oxidation in potato (Solanum tuberosum) tubers [O] . Galliard, T., Wardale, D. A., Matthew, J. A. 1974

机译：马铃薯（Solanum tuberosum）块茎亚油酸氧化脂氧合酶途径中的不饱和脂肪酸醚中间体-烯乙酸的酶促和非酶促降解

Kinetic Isotope H/D Effect in the Oxidation of Ethers of Linoleic Acid in Solutions

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