Simultaneous removal of NO (x) and SO2 by low-temperature selective catalytic reduction over modified activated carbon catalysts

摘要

A series of modified porous activated carbon (AC) catalysts prepared by impregnation were investigated for the low-temperature (250A degrees C) selective catalytic reduction (SCR) of NO (x) with NH3 with simultaneous removal of SO2. The effects of various preparation conditions and reaction conditions on NO and SO2 conversions were observed, such as support type, active components, copper loading, calcination temperature and presence of H2O and O-2. The modified AC catalysts were characterized by BET, XRD, TG and TPX methods. The activity test results showed that the optimal catalyst is 15% Cu/WCSAC which can provide 52% NO conversion and 68% SO2 conversion simultaneously at 175A degrees C with a space velocity of 30000 h(aEuro'1), and the optimal calcination temperature was 500A degrees C. The presence of H2O could inhibit NO conversion and promote the SO2 conversion. The effect of O-2 (0-5%) was evaluated, and the NO and SO2 conversions were best when the concentration of O-2 was 3%. Research demonstrated that Cu/WCSAC catalyst was a kind of potential catalysts due to the amorphous phase, high specific areas and high active ability.