Effect of Association on Nucleophilic Addition of (Meth)acrylic Aminoamides to Acrylic Acids in Aqueous Solutions

Kazantsev O. A.; Baruta D. S.; Kamorin D. M.; Shirshin K. K.; Sivokhin A. P.

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Effect of Association on Nucleophilic Addition of (Meth)acrylic Aminoamides to Acrylic Acids in Aqueous Solutions

机译：（甲基）丙烯酸氨基酰胺与水溶液中丙烯酸的亲核加成的效果

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Reactions of nucleophilic addition of N-(3-dimethylaminoalkyl)(meth)acrylamides to acrylic, N-acryloylaminoacetic, and 2-acrylamido-2-methylpropanesulfonic acid with the formation of betaines revealed an unusual dependence of the initial rate and equilibrium conversion on concentration of the reagents. The observed effects were explained by structural features of the reagents and the products.

机译：用形成甜菜碱的形成N-（3-二甲基氨基烷基）（甲基）丙烯酰胺与丙烯酸，N-丙烯酰基氨基酸和2-丙烯酰胺-2-甲基丙二酸的反应揭示了初始速率和均衡转化对浓度的不寻常依赖性试剂。观察到的效果是通过试剂和产品的结构特征来解释的。

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来源
《Russian Journal of General Chemistry》 |2018年第4期|共5页
作者
Kazantsev O. A.; Baruta D. S.; Kamorin D. M.; Shirshin K. K.; Sivokhin A. P.;
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作者单位

RE Alekseev Nizhny Novgorod State Tech Univ Ul Minina 24 Nizhnii Novgorod 603950 Russia;

RE Alekseev Nizhny Novgorod State Tech Univ Ul Minina 24 Nizhnii Novgorod 603950 Russia;

RE Alekseev Nizhny Novgorod State Tech Univ Ul Minina 24 Nizhnii Novgorod 603950 Russia;

RE Alekseev Nizhny Novgorod State Tech Univ Ul Minina 24 Nizhnii Novgorod 603950 Russia;

RE Alekseev Nizhny Novgorod State Tech Univ Ul Minina 24 Nizhnii Novgorod 603950 Russia;

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正文语种 eng
中图分类化学;
关键词
N-(3-dimethylaminoalkyl)metacrylamides; acrylic acid; N-acryloylaminoacetic acid; 2-acrylamido-2-methylpropanesulfonic acid; betaines;

机译：N-（3-二甲基氨基烷基）丙烯酰胺;丙烯酸;N-丙烯酰基氨基乙酸;2-丙烯酰胺-2-甲基丙二磺酸;甜菜碱;

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专利

1. Effect of Association on Nucleophilic Addition of (Meth)acrylic Aminoamides to Acrylic Acids in Aqueous Solutions [J] . Kazantsev O. A., Baruta D. S., Kamorin D. M., Russian Journal of General Chemistry . 2018,第4期

机译：（甲基）丙烯酸氨基酰胺与水溶液中丙烯酸的亲核加成的效果
2. Effect of Reactant Association on Addition of Tertiary Amines to Acrylic Acid in Aqueous Solutions [J] . A.P.Malyshev, K.V.Shirshin, O.A.Kazantsev Russian journal of applied chemistry . 2006,第10期

机译：反应物缔合对水溶液中叔胺加成丙烯酸的影响
3. Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution [J] . Yucheng Dong, Zhentao Wang, Chaozhong Li Nature Communications . 2017,第1期

机译：水溶液中聚（甲基）丙烯酸的受控自由基氟化
4. Michael Addition Reactions between Nucleophilic GlycineEquivalents and Acrylic Acid Derivatives as a Practicaland Generalized Approach to the Asymmetric Synthesisof II-Substituted-a-Amino Acids [C] . Vadim A. Soloshonok, Hisanori Ueki, Trevor K. Ellis ACS symposium asymmetric synthesis and application of α-amino acids . 2009

机译：亲核糖糖糖尿剂与丙烯酸衍生物之间的迈克尔添加反应作为不对称合成的不对称 - A-氨基酸的不对称方法的普遍化方法
5. Rheology and interfacial properties of aqueous solutions of the diblock polyelectrolyte poly(styrene-block-acrylic acid). [D] . Kimerling, Abigail. 2007

机译：二嵌段聚电解质聚（苯乙烯嵌段丙烯酸）的水溶液的流变学和界面性质。
6. Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution [O] . Yucheng Dong, Zhentao Wang, Chaozhong Li -1

机译：水溶液中聚（甲基）丙烯酸的受控自由基氟化
7. Temperature and pH-Dependent Response of Poly(Acrylic Acid) and Poly(Acrylic Acid-co-Methyl Acrylate) in Highly Concentrated Potassium Chloride Aqueous Solutions [O] . Aleksander Sinek, Maria Kupczak, Anna Mielańczyk, 2020

机译：聚（丙烯酸）和聚（丙烯酸 - 甲基丙烯酸酯）高浓氯化钾水溶液的温度和pH依赖性响应
8. Reactivities of Acrylic and Methacrylic Acids in a Nucleophilic Addition Model of Their Biological Activity (Journal Version) [R] . Osman, R. , Namboodiri, K. , Weinstein, H. , 1988

机译：丙烯酸和甲基丙烯酸在其生物活性的亲核加成模型中的反应性（期刊版）

Effect of Association on Nucleophilic Addition of (Meth)acrylic Aminoamides to Acrylic Acids in Aqueous Solutions

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