Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes

Nuraneeva E. N.; Guseva G. B.; Antina E. V.

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Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes

机译：卤化特征对单碘和二溴二甲基锌（II）复合物稳定性的影响

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The complex formation of zinc(II) acetate with monoiodo- and dibromo-substituted dipyrromethenes in DMF at 298.15 K were studied by means of spectrophotometric titration. It was found that the process involves consecutive formation of heteroligand [ZnLOAc] and homoligand [ZnL2] complexes. The thermodynamic stability of halogenated zinc(II) dipyrrolylmethenates [ZnL2] was studied.

机译：通过分光光度滴定研究了在298.15k中在298.15k中在DMF中与单碘 - 和二溴取代的偶氮二甲磺酸锌的复合物形成。发现该方法涉及杂环[ZnLOAc]和优质配合物的连续形成。研究了卤代锌（II）偶氮基甲醇酯[ZnL2]的热力学稳定性。

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《Russian Journal of General Chemistry》 |2017年第7期|共7页
作者
Nuraneeva E. N.; Guseva G. B.; Antina E. V.;
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Russian Acad Sci GA Krestov Inst Solut Chem Ul Akad Skaya 1 Ivanovo 153045 Russia;

Russian Acad Sci GA Krestov Inst Solut Chem Ul Akad Skaya 1 Ivanovo 153045 Russia;

Russian Acad Sci GA Krestov Inst Solut Chem Ul Akad Skaya 1 Ivanovo 153045 Russia;

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1. Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes [J] . Nuraneeva E. N., Guseva G. B., Antina E. V. Russian Journal of General Chemistry . 2017,第7期

机译：卤化特征对单碘和二溴二甲基锌（II）复合物稳定性的影响
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Effect of halogenation features on the stability of Zinc(II) complexes with monoiodo- and dibromodipyrromethenes

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