Self-Assembling in the Systems MX2-2-(7-Bromo-2-oxo-5-phenyl-2,3-dihydro-1H-1,4-benzdiazepin-1-yl) acetohydrazide-Salicyl Aldehyde (M =Co, Ni, Zn; X = Cl, CH3COO)

摘要

By self-assembling in the systems MX2-2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1H-1,4-benzdiazepin-1-yl) acetohydrazide (Hydr)-salicyl aldehyde (HSal) (M= Co, Ni, Zn; X = Cl, CH3COO) the complexes of composition [ Co(HydrSal)(2)], [ Ni(HydrSal)(2)], [ Zn(HydrHSal) Cl-2], [ Zn(HydrSal)(CH3COO)(H2O)] have been synthesized. The local atomic structure of the coordination unit was determined by the method of X-ray absorption spectroscopy. Thermal stability, electroconductivity, and magnetic susceptibility of the complexes have been studied.