Alkylation of 1-(Prop-2-ynyl)piperidine with CH-Acids in ihe Presence of Mercury(II) Acetate

Hobosyan N. G.; Balyan K. V.; Petrosyan A. L.; Hovakimyan S. A.; Chobanyan Zh. A.; Nersisyan R. S.

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Alkylation of 1-(Prop-2-ynyl)piperidine with CH-Acids in ihe Presence of Mercury(II) Acetate

机译：1-（PROP-2-炔基）哌啶与CH酸中的醋酸汞（II）乙酸酯的烷基化

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General regilarities of the reaction of C-nucleophiles with 1-(prop-2-ynyl) piperidine in the presence of mercuty(II) acetate to form mono-and dicarbonyl derivatives of piperidine and bis[3-(piperidin-1-yl)prop-1ynyl] mercury. Conditions of these reactions were optimized.

机译：C-（PROP-2-炔基）哌啶在甲丙酯存在下用1-（PROP-2-炔基）哌啶反应的通用晶粒，形成哌啶的单 - 和二羰基衍生物[3-（哌啶-1-基） prop-1ynynyl]汞。这些反应的条件被优化。

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来源
《Russian Journal of General Chemistry》 |2017年第1期|共4页
作者
Hobosyan N. G.; Balyan K. V.; Petrosyan A. L.; Hovakimyan S. A.; Chobanyan Zh. A.; Nersisyan R. S.;
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作者单位

Natl Acad Sci Armenia Ctr Organ &

Pharmaceut Chem Inst Organ Chem Res &

Technol Pr Azatutyan 26 Yerevan 0014 Armenia;

Natl Acad Sci Armenia Ctr Organ &

Pharmaceut Chem Inst Organ Chem Res &

Technol Pr Azatutyan 26 Yerevan 0014 Armenia;

Natl Acad Sci Armenia Ctr Organ &

Pharmaceut Chem Inst Organ Chem Res &

Technol Pr Azatutyan 26 Yerevan 0014 Armenia;

Abobyan Armenian State Pedag Univ Yerevan Armenia;

Natl Acad Sci Armenia Ctr Organ &

Pharmaceut Chem Inst Organ Chem Res &

Technol Pr Azatutyan 26 Yerevan 0014 Armenia;

Natl Acad Sci Armenia Ctr Organ &

Pharmaceut Chem Inst Organ Chem Res &

Technol Pr Azatutyan 26 Yerevan 0014 Armenia;

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正文语种 eng
中图分类化学;
关键词
alkylatione; acetylacetone; acetoacetic ester; prototropic isomers;

机译：烷基化;乙酰丙酮;乙酰乙酸酯;原激官异构体;

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1. Alkylation of 1-(Prop-2-ynyl)piperidine with CH-Acids in ihe Presence of Mercury(II) Acetate [J] . Hobosyan N. G., Balyan K. V., Petrosyan A. L., Russian Journal of General Chemistry . 2017,第1期

机译：1-（PROP-2-炔基）哌啶与CH酸中的醋酸汞（II）乙酸酯的烷基化
2. Manganese(iii) acetate-mediated activation of C-H bonds of weak CH-acids; addition of o-carborane, its derivatives, and some other CH-acids to [60]-fullerene [J] . Tumanskii Boris L., Sabirov Denis S., Solodovnikov Stanislav P., Dalton transactions: An international journal of inorganic chemistry . 2019,第6期

机译：锰（III）醋酸锰介导的弱CH酸的C-H键的活化; 添加O-碳硼烷，其衍生物和一些其他CH-酸至[60] - 氟联
3. 1,3-Dipolar cycloadditions:Part II-Cycloaddition of 1-pyrroline 1-oxide to 1-cinnamoyl piperidine and 1-(4'-chlorocinnamoyl)piperidine [J] . Avijit Banerji, Piyali Sengupta, Alain Neuman, Indian Journal of Chemistry, Section B. Organic Including Medicinal . 1998,第1期

机译：1,3-偶极环加成反应：第二部分-1-吡咯啉一氧化物与1-肉桂酰基哌啶和1-（4'-氯肉桂酰基）哌啶的环加成反应
4. Synthesis of 1-(4-Antipyrine)-3-(3-Nitroaniline)-Triazene and Its Color Reaction with Mercury(II) [C] . CHEN Wen-bin, MA Wei-xing, XU Xing-you SSITE International Conference on Future Material Research and Industry Application . 2012

机译：合成1-（4-抗纤维素）-3-（3-硝基苯胺） - 三氮杂物及其与汞的颜色反应（II）
5. I. Dearomatization of furans via [2,3]-Still-Wittig rearrangement. II. Palladium(II)- and mercury(II)-catalyzed rearrangement of substituted 1-ethynyl-2-propenyl acetates. III. Progress toward the synthesis of the terpestacin cyclopentenone core via Nazarov cyclization [D] . Caruana, Patrick Anthony 2007

机译：I.通过[2，3] -Still-Wittig重排使呋喃脱芳香化。二。钯（II）和汞（II）催化的乙酸1-乙炔基-2-丙烯基乙酸酯的重排。三，纳扎罗夫环化合成萜品碱环戊烯酮核心的进展
6. {N′-1-(2-Pyridyl)ethylidene-κNbenzohydrazidato-κ2 N′O}{N′-1-(2-pyridyl)ethylidene-κNbenzohydrazide-κ2 N′O}copper(II) trichloroacetate [O] . Amitabha Datta, Nien-Tsu Chuang, Yun-Sheng Wen, 2011

机译：{N-1-（2-吡啶基）乙基亚乙基-κN苯并肼基-κ2 NO} {N-1-（2-吡啶基）乙基亚乙基-κN苯甲酰肼-κ2 NO}三氯乙酸铜（II）
7. Studies on Photochemical Alkylation of Inorganic Mercury. II. Alkylation of Inorganic Mercury in Water by Irradiation with Sunlight or Blacklight [O] . HIROKATSU AKAGI, YONEJI SAKAGAMI 1972

机译：无机汞的光化学烷基化研究。 II。用阳光或黑光照射的水中无机汞的烷基化

Alkylation of 1-(Prop-2-ynyl)piperidine with CH-Acids in ihe Presence of Mercury(II) Acetate

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