Vinylation of Selected Terpenols with Calcium Carbide

Rodygin K. S.

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Vinylation of Selected Terpenols with Calcium Carbide

机译：选择碳化钙的选定三萜醇的致乙烯化酶

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A method for the synthesis of vinyl derivatives of the terpenols verbenol and fenchol by their reaction with calcium carbide was developed. It was found that addition of potassium fluoride affects the yield of nucleophilic addition of the corresponding alcoholate ions to acetylene.

机译：开发了通过与碳化钙的反应合成三萜醇瓦上醇和卵醇的乙烯基衍生物的方法。发现氟化钾的添加影响将相应的醇化物离子的亲核加入对乙炔的产率。

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来源
《Russian Journal of General Chemistry》 |2017年第12期|共3页
作者
Rodygin K. S.;
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作者单位

St Petersburg State Univ Univ Skii Pr 26 St Petersburg 198504 Russia;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
vinyl ether; calcium carbide; verbenol; fenchol;

机译：乙烯基醚;碳化物;verbenol;fenchol;

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专利

1. Vinylation of Selected Terpenols with Calcium Carbide [J] . Rodygin K. S. Russian Journal of General Chemistry . 2017,第12期

机译：选择碳化钙的选定三萜醇的致乙烯化酶
2. An efficient metal-free pathway to vinyl thioesters with calcium carbide as the acetylene source (vol 18, pg 482, 2016) [J] . Rodygin Konstantin S., Ananikov Valentine P. Green chemistry . 2020,第16期

机译：一种高效的金属无金属途径，含有碳化钙作为乙炔源（Vol 18，PG 482,2016）
3. Direct Synthesis of Deuterium-Labeled O -, S -, N -Vinyl Derivatives from Calcium Carbide [J] . Ledovskaya Maria S., Voronin Vladimir V., Rodygin Konstantin S., Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2019,第15期

机译：直接合成来自碳化钙的氘标记的O - ，S - ，N-乙烯基衍生物
4. Comparative Study of Mechanical Behavior of Silicon Carbide Filled and Boron Carbide Filled Glass Fiber Reinforced Vinyl Ester Composites [C] . Sudheer D. Kulkarni, S. Chethan International Conference on Polymer Composites . 2018

机译：碳化硅填充碳化硅机械行为的比较研究和硼碳化物填充玻璃纤维增强乙烯基酯复合材料
5. Copper Promoted Coupling of Vinyl Boronates with Alcohols: A Mild Synthesis of Allyl Vinyl Ethers and Cellular Imaging and Synthesis of the Calcium Sensor Fluoresceindigalactose-Bisaminophenoxyethane-N,N,N',N'-Tetraacetic Acid-Acetoxymethyl Ester [D] . Shade, Ryan Edward 2010

机译：铜促进乙烯基硼酸酯与醇的偶联：烯丙基乙烯基醚的轻度合成和细胞成像以及钙传感器荧光二乳糖-双氨基苯氧基乙烷-N，N，N'，N'-四乙酸-乙酰氧基甲基酯的合成
6. Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials [O] . Konstantin S. Rodygin, Alexander S. Bogachenkov, Valentine P. Ananikov 2018

机译：二级胺核与碳化钙的乙烯基化用于高效的后改性和获得聚合物材料
7. Correction: An efficient metal-free pathway to vinyl thioesters with calcium carbide as the acetylene source [O] . Konstantin S. Rodygin, Valentine P. Ananikov 2020

机译：校正：与碳化钙的乙烯基硫代乙烯酯作为乙炔源的有效金属途径
8. PREPARATION OF CALCIUM BY THE DISSOCIATION OF CALCIUM CARBIDE [R] . A. S. Mikulinskii, F. S. Maron 1961

机译：碳化钙离解制备钙

Vinylation of Selected Terpenols with Calcium Carbide

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