The Phenomenology of the Solid-Electrolyte Interface.III.The Concept of Double Electric Layer Correlated with the Structure and Phenomenology of the Polarized Interface

摘要

By ignoring the structure,the orienting possibilities and the solvent polar molecule functionability,the current models for a double electrical layer become rigid,anachronical and non -functional related to the interface phenomenology.For the polarised electrode,the structured area between the PHI and PHE (taken into consideration from the point of view of the Bockris model for a double electrical layer) is actually composed of two structured "transition phases":the Internal Structured Layer (ISL),conductor,extensivble in solution with the increase of the applied potential (until reaching the electrolysis limit) and the External Structured Layer (ESL),depending on the solution concentration,responsible of the occurence of the electrode potential.The limit between them is marked by the appearance of a counter-ionic maximum in the background noise from the current-time recordings.The background noise becomes,thus,an information source that leads to a phenomenologic model for the polarised interface,in agreement with the experiments.