首页> 外文期刊>Reaction kinetics,mechanisms and catalysis >Synthesis and characterization of Cu-N, N '-Dicyclohexylcarbodiimide supported on CMK-3 as a novel, efficient and recoverable nanocatalyst for synthesis of tetrazole, polyhydroquinoline, and sulfoxide derivatives
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Synthesis and characterization of Cu-N, N '-Dicyclohexylcarbodiimide supported on CMK-3 as a novel, efficient and recoverable nanocatalyst for synthesis of tetrazole, polyhydroquinoline, and sulfoxide derivatives

机译:CMK-3负载Cu-N,N'-二环己基碳二亚胺的合成与表征,作为一种新的,有效且可回收的纳米催化剂,用于合成四唑,多羟基喹啉和亚砜衍生物

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摘要

Mesoporous carbon CMK-3 was prepared using SBA-15 silica mesoporous as a hard template. Then, Cu-N, N '-Dicyclohexylcarbodiimide was supported on CMK-3 as a reusable and highly efficient nanocatalyst for the synthesis of tetrazole, polyhydroquinoline, and sulfoxide derivatives. This new catalyst was characterized by FT-IR spectroscopy, XRD, SEM, BET, TGA, EDX, and ICP-OES techniques. After completing reactions, the catalyst was easily separated from the reaction mixture using centrifuge and reusable five times without significant loss of their catalytic efficiency.
机译:使用SBA-15二氧化硅作为硬模板制备介孔碳CMK-3。 然后,将Cu-N,N'-二氯己基碳酸基二酰亚胺作为可重复使用和高效的纳米催化剂,用于合成四唑,多羟基喹啉和亚砜衍生物。 该新催化剂的特征在于FT-IR光谱,XRD,SEM,BET,TGA,EDX和ICP-OES技术。 在完成反应后,使用离心机和可重复使用的五次,容易将催化剂与反应混合物分离,而不会显着损失其催化效率。

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