Crystal structure and luminescence properties of the blue-green-emitting Ba-9(Lu, Y)(2)Si6O24:Ce3+ phosphor

摘要

Samples of the Ba-9(Lu2-xYx)Si6O24:Ce3+ (x=0-2) blue-green phosphors were synthesized by solid-state reactions. All the samples exhibited a rhombohedral crystal structure. As the Y3+ concentration increased, the diffraction peaks shifted to the small angle region and the lattice parameters increased due to the larger ionic radius of Y3+ (r=0.900 angstrom) compared with that of Lu3+ (r=0.861 angstrom). Under 400nm excitation, samples exhibited strong blue-green emissions around 490nm. The emission bands had a slight blue shift that resulted from weak crystal-field splitting with increasing Y3+ concentration. Luminescence intensity and quantum efficiency (QE) decreased with increasing Y3+ concentration. The internal QE decreased from 74 to 50% and the external QE decreased from 50 to 34% as x increased from 0 to 2. The thermal stability of the Lu series was better than that of the Y-series. The excitation band peak around 400nm matched well with the emission light from the efficient near-ultraviolet (NUV) chip. These results indicate promising applications for these NUV-based white light-emitting diodes.