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Nanocrystal synthesis, mu fluidic sample dilution and direct extraction of single emission linewidths in continuous flow

机译:纳米晶合成,亩流体样品稀释,直接提取连续流动的单一排放线宽

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The rational design of semiconductor nanocrystal populations requires control of their emission linewidths, which are dictated by interparticle inhomogeneities and single-nanocrystal spectral linewidths. To date, research efforts have concentrated on minimizing the ensemble emission linewidths, however there is little knowledge about the synthetic parameters dictating single-nanocrystal linewidths. In this direction, we present a flow-based system coupled with an optical interferometry setup for the extraction of single nanocrystal properties. The platform has the ability to synthesize nanocrystals at high temperature <300 degrees C, adjust the particle concentration after synthesis and extract ensemble-averaged single nanocrystal emission linewidths using flow photon-correlation Fourier spectroscopy.
机译:半导体纳米晶体群的理性设计需要控制其排放线宽,其被颗粒间不均匀性和单纳米晶体光谱线宽决定。 迄今为止,研究努力集中在最小化集合排放线宽,但是关于单纳米晶体线宽的合成参数几乎没有了解。 在这种方向上,我们介绍了一种基于流动的系统,其与光学干涉测定装置耦合,用于提取单纳米晶体性质。 该平台能够在高温<300℃下合成纳米晶体,通过流动光子相关傅里叶光谱,在合成后的颗粒浓度调节合成和提取集合平均的单纳米晶体发射线宽。

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