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Tartrate- and imidazole-derlved diketones and diols: preparation and stability constants of their Cu~(2+) complexes

机译:酒石酸酯和咪唑 - Derlved Diketone和二醇:其Cu〜(2+)复合物的制备和稳定性常数

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摘要

Overall, six tartrate- and imidazole-derived ketones and diols were synthesized in a stepwise manner as model compounds for the coordination of Cu~(2+) ions. The stability constants of copper(II) complexes were studied spectrophotometrically. It was found that the two model structures coordinate Cu~(2+) ions differentially.
机译:总体而言,以逐步的方式作为用于Cu〜(2+)离子的配位的模型化合物以逐步的方式合成六种酒石酸和咪唑衍生的酮和二醇。 分光光度法研究了铜(II)复合物的稳定性常数。 发现两种模型结构差异地坐标Cu〜(2+)离子。

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  • 来源
    《Monatshefte fur Chemie》 |2011年第11期|共6页
  • 作者单位

    Institute of Organic Chemistry and Technology. Faculty of Chemical Technology University of Pardubice Studentska 573 53210 Pardubice. Czech Republic;

    Institute of Organic Chemistry and Technology. Faculty of Chemical Technology University of Pardubice Studentska 573 53210 Pardubice. Czech Republic;

    Institute of Organic Chemistry and Technology. Faculty of Chemical Technology University of Pardubice Studentska 573 53210 Pardubice. Czech Republic;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

    Heterocycles; Ligands; Stability constant; Metal complexes; UV/vis spectroscopy;

    机译:杂环;配体;稳定性恒定;金属配合物;UV / Vis光谱;

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