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Geochemical characteristics of light hydrocarbons and their influencing factors in natural gases of the Kuqa Depression, Tarim Basin, NW China

机译:塔里木盆地塔姆盆地天然气中轻质碳氢化合物的地球化学特征及其影响因素

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In order to determine the source of the light hydrocarbons in the Kuqa Depression of the Tarim Basin, Northwest China, their geochemical characteristics are documented, and possible influencing factors are discussed in a broad context on the basis of geochemical analyses of natural gas samples from 19 wells in combination with previously reported natural gas components and carbon isotope values from the same depression. The biomarker analytical results show that (a) methyl cyclohexane (37.5-60.3%) of natural gas predominates the C-7 light hydrocarbon series (methyl cyclohexane, heptanes, and dimethyl cyclopentane), and (b) the heptane content (25.0-54.8%) is also relatively high. The C6-7 light hydrocarbon series (aromatics, normal alkanes, and cycloalkanes) have abnormally high aromatics (benzene and toluene) content (26.2-83.8%). Heptane value (13.31-37.77%) and isoheptane value (2.10-7.64%) indicate that the Kuqa natural gases are of high maturity and typical of coal-derived gas (gas generated by sapropelic source rock). Their light hydrocarbons, however, appear to have some characteristics of mixed-source organic matter. Specifically, the light hydrocarbons in the Dina 2 gas field show characteristics of the coal-derived gas; those in the Dabei gas field show some features of the oil-associated gas (gas generated by humic source rock), whereas those in the Kela 2 and Keshen 2 gas fields and Well Yangtake-101 display characteristics of the mixed source organic matter. The abnormally high content of the aromatics in the Kuqa Depression may have resulted mainly from their high productivity during the thermal maturity of humic type organic matters and the gases accumulation of late stage. The different relative contents of the aromatics in various oil and gas fields may have been accounted by different organic matter types, maturity, and distribution patterns of source rocks.
机译:为了确定塔里木盆地塔里木盆地的轻质烃的来源,他们的地球化学特征被记录,并且在广泛的背景下,在19种自然气体样本的地球化学分析的基础上讨论了可能的影响因素。井与先前报告的天然气成分和来自同一抑郁症的碳同位素值组合。生物标志物分析结果表明(a)天然气甲基环己烷(37.5-60.3%),其占C-7光源系列(甲基环己烷,庚烷和二甲醚),和(B)庚烷含量(25.0-54.8 %)也相对较高。 C6-7轻质烃系列(芳烃,正烷烃和环烷烃)具有异常高的芳族化学(苯和甲苯)含量(26.2-83.8%)。庚烷值(13.31-37.77%)和异庚烷值(2.10-7.64%)表明Kuqa天然气具有高成熟度和典型的煤衍生气体(Sapropelic Source Rock产生的气体)。然而,它们的光烃似乎具有混合源有机物的一些特征。具体地,DINA 2气体场中的光烃显示出煤衍生气体的特征; Dabei气田中的那些展示了油相关气体(腐殖源岩产生的气体)的一些特征,而那些在Kela 2和Keshen 2天然气场和阳早-101的阳台 - 101显示混合源有机物质的特征。 Kuqa凹陷中的芳烃的异常高含量可能主要从其高生产率期间在腐殖液有机物质的热成熟期间和晚期的气体积累期间产生的高生产率。各种石油和天然气场中芳烃的不同相对内容可能已被源岩的不同有机物质类型,成熟度和分布图案占据。

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