Effects of Al content on the corrosion properties of Mg–4Y– <i >xx Al alloys

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Effects of Al content on the corrosion properties of Mg–4Y– xx Al alloys
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机译：Al含量对MG-4Y的腐蚀特性的影响 x x Al合金
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Abstract > The corrosion performances of Mg–4Y– x Al ( x ?=?1, 2, 3, and 4?wt%) alloys in the 3.5% NaCl electrolyte solution are investigated by electrochemical tests, weight loss measurement and corrosion morphology observation. The results indicate that corrosion modes for the alloys are localized corrosion and the filiform type of attack. With Al concentration increasing from 1 to 4 wt%, the corrosion rate of Mg–4Y– x Al alloys decreases firstly and then increases, and WA42 alloy shows the best corrosion resistance. The addition of Al element to Mg–4Y alloys leads to the formation of Al <sub>2</sub> Y and Al <sub>11</sub> Y <sub>3</sub> intermetallic compounds and reduces the proportion of Mg <sub>24</sub> Y <sub>5</sub> phase. Corrosion resistance of the Mg–4Y– x Al alloys mainly depends on the size and distribution of the second phases. Besides, the addition of excessive Al can greatly consumes the Y element in the matrix, thus leading to a less protective film on the alloys. The effect of the relative Volta potential changes between the second phases and α‐Mg on corrosion resistance of Mg–4Y– x Al alloys is insignificant. The main corrosion products of the Mg–4Y– x Al alloys are Mg(OH) <sub>2</sub> , Mg <sub>3</sub> (OH) <sub>5</sub> Cl·4H <sub>2</sub> O, Mg <sub>0.72</sub> Al <sub>0.28</sub> (CO <sub>3</sub> ) <sub>0.15</sub> (OH) <sub>1.98</sub> (H <sub>2</sub> O) <sub>0.48</sub> , and Mg <sub>4</sub> Al <sub>2</sub> (OH) <sub>12</sub> CO <sub>3</sub> ·3H <sub>2</sub> O. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XML：lang =“en”type =“main”> <标题类型=“main”>抽象</ title> > mg-4y的腐蚀性能 - x </ i> AL（ x </ i> 通过电化学试验研究3.5％NaCl电解质溶液中的3.5％NaCl电解质溶液中的合金，减肥测量和腐蚀形态观察。结果表明，合金的腐蚀模式是局部腐蚀和丝状侵蚀类型。 al浓度从1〜4wt％增加，Mg-4Y的腐蚀速率 x </ i> Al合金首先降低，然后增加，并且WA42合金显示出最佳耐腐蚀性。向Mg-4Y合金中添加Al元素导致Al的形成 <sub> 2 </ sub> y和al. <sub> 11 </ sub> y <sub> 3 </ sub> 金属间化合物并减少mg的比例 <sub> 24 </ sub> y <sub> 5 </ sub> 阶段。 Mg-4Y的耐腐蚀性 - x </ i> Al合金主要取决于第二阶段的大小和分布。此外，添加过量的Al可以大大消耗基质中的Y元素，从而导致合金上的保护性薄膜。第二阶段和α-Mg之间的相对电压变化的影响Mg-4Y-耐腐蚀性 - x </ i> Al合金是微不足道的。 MG-4Y的主要腐蚀产品 - x </ i> Al合金是mg（哦） <sub> 2 </ sub> ，mg <sub> 3 </ sub> （哦） <sub> 5 </ sub> CL·4H. <sub> 2 </ sub> 我的天啊 <sub> 0.72 </ sub> AL. <sub> 0.28 </ sub> （CO. <sub> 3 </ sub> 的） <sub> 0.15 </ sub> （哦） <sub> 1.98 </ sub> （H <sub> 2 </ sub> o） <sub> 0.48 </ sub> 和mg. <sub> 4 </ sub> AL. <sub> 2 </ sub> （哦） <sub> 12 </ sub> CO. <sub> 3 </ sub> ·3H. <sub> 2 </ sub> O. </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24514/'>《Materials and Corrosion》</a> <b style="margin: 0 2px;">|</b><span>2020年第7期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7194.html" title="金属腐蚀与保护、金属表面处理">金属腐蚀与保护、金属表面处理;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=corrosion properties&option=203" rel="nofollow">corrosion properties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemical measurements&option=203" rel="nofollow">electrochemical measurements;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=immersion tests&option=203" rel="nofollow">immersion tests;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mg–4Y– x Al alloys&option=203" rel="nofollow">Mg–4Y– x Al alloys;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=microstructure&option=203" rel="nofollow">microstructure;</a> </p> <div class="translation"> 机译：腐蚀特性;电化学测量;浸渍试验;Mg-4Y-x Al合金;微观结构; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐滨士&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,徐滨士</a> <span> <a href="/conference-cn-9759/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . “十二五”堆焊、热喷涂及表面工程技术发展前瞻学术会议 </a> <span> <span> . 2011</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031424935.html">熔体热历史对Al合金凝固特性影响的分子动力学模拟</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王少刚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王少刚</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120113766876.html">一种测试Al含量对MgNiAl储氢合金影响的测试系统</a> <b>[P]</b> . <span> 中国专利： CN113777267A </span> <span> . 2021-12-10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120113781504.html">一种测试Al含量对MgNiAl储氢合金影响的试验方法</a> <b>[P]</b> . <span> 中国专利： CN113791099A </span> <span> . 2021-12-14</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130435062206.html">Ferrous alloy with high chromium content, used in roller bearings for aircraft, shows combination of good mechanical properties, low wear, low roll contact fatigue and good corrosion resistance</a> <b>[P]</b> . <span> 外国专利：  AT502397A4 </span> <span> . 2007-03-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：高铬含量的亚铁合金，用于飞机的滚动轴承，具有良好的机械性能，低磨损，低滚动接触疲劳性和良好的耐腐蚀性 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130418729354.html">Ni-BASED ALLOY EXCELLENT IN HOT FORGING PROPERTY, HIGH TEMPERATURE OXIDATION RESISTANCE AND HIGH TEMPERATURE HALOGEN GAS CORROSION PROPERTY AND MEMBER USING Ni-BASED ALLOY</a> <b>[P]</b> . <span> 外国专利：  JP2014080675A </span> <span> . 2014-05-08</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：镍基合金在热锻造性能，高温抗氧化性和高温卤化气体腐蚀性能以及使用镍基合金的构件方面表现出色 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130408765599.html">7XX IMPROVED 7XX ALUMINUM CASTING ALLOYS AND METHODS FOR MAKING THE SAME</a> <b>[P]</b> . <span> 外国专利：  KR20170002473A </span> <span> . 2017-01-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：7XX改进的7XX铝合金铸造合金及其制造方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> 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Effects of Al content on the corrosion properties of Mg–4Y– xx Al alloys

摘要