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The influence of iron and cobalt on the type II hot corrosion behavior of NiCr model alloys

机译：铁和钴对NICR模型合金II型热腐蚀行为的影响

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Abstract > The type II hot corrosion behavior of the alloys NiCr20, NiCr20Co10, and NiCr20Fe10 is investigated at 700°C in synthetic air?+?0.5% SO <sub>2</sub> for up to 300?hr. Pure Na <sub>2</sub> SO <sub>4</sub> and a eutectic mixture of MgSO <sub>4</sub> –Na <sub>2</sub> SO <sub>4</sub> are applied as deposits. The kinetics are investigated via dimensional metrology and correlated to the microstructural progression of the corrosion by examining the cross‐sections. All alloys exhibit two‐stage corrosion kinetics, with initially low and subsequently increased metal losses. Independent of the deposit composition, the metal loss after the longest exposure time is increased by the alloying element cobalt, whereas it is decreased for the iron‐containing alloy. All alloys show increased metal losses when exposed to the MgSO <sub>4</sub> –Na <sub>2</sub> SO <sub>4</sub> deposit. The time to the propagation stage is similar for all tests. During the stage of low metal loss, all alloys develop a chromia scale and internal chromium sulfides. When the propagation stage is reached, chromium and nickel can be found along with oxygen and sulfur within the pit. Nickel is dissolved into the deposit, where it precipitates. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 在合成空气中在700℃下研究了合金NicR20，NiCR20CO10和NICR20FE10的II型热腐蚀行为？+ 0.5％ <sub> 2 </ sub> 最多300？小时。纯NA. <sub> 2 </ sub> 所以 <sub> 4 </ sub> 和mgso的共晶混合物 <sub> 4 </ sub> - <sub> 2 </ sub> 所以 <sub> 4 </ sub> 适用为存款。通过尺寸计量来研究动力学，通过检查横截面来研究与腐蚀的微观结构进展相关。所有合金都表现出两级腐蚀动力学，最初较低，随后增加了金属损失。独立于沉积物组合物，通过合金元素钴增加了最长的暴露时间后的金属损失，而含铁合金则降低。所有合金均在暴露于MgSO时显示出增加的金属损失 <sub> 4 </ sub> - <sub> 2 </ sub> 所以 <sub> 4 </ sub> 订金。传播阶段的时间与所有测试相似。在低金属损失的阶段，所有合金都会发生染色量和内部硫化物。当达到繁殖阶段时，可以在坑内和氧和硫相处找到铬和镍。镍溶解在沉积物中，在沉淀物中沉淀。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24514/'>《Materials and Corrosion》</a> <b style="margin: 0 2px;">|</b><span>2020年第7期</span><b style="margin: 0 2px;">|</b><span>共14页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7194.html" title="金属腐蚀与保护、金属表面处理">金属腐蚀与保护、金属表面处理;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fireside corrosion&option=203" rel="nofollow">fireside corrosion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hot corrosion&option=203" rel="nofollow">hot corrosion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nickel‐based alloy&option=203" rel="nofollow">nickel‐based alloy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sodium sulfate&option=203" rel="nofollow">sodium sulfate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=type II&option=203" rel="nofollow">type II;</a> </p> <div class="translation"> 机译：炉边腐蚀;热腐蚀;镍基合金;硫酸钠;II型; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023575121.html">The influence of iron and cobalt on the type II hot corrosion behavior of NiCr model alloys</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-24514/" target="_blank" rel="nofollow" class="tuijian_authcolor">Materials and Corrosion .</a> <span>2020</span><span>,第7期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铁和钴对NICR模型合金II型热腐蚀行为的影响</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704012921152.html">Influence of acetate ions and the role of the diluents on the extraction of copper (II), nickel (II), cobalt (II), magnesium (II) and iron (II, III) with different types of extractants</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=I. 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href="/conference-cn-20604/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十一届中国高温合金年会 </a> <span> <span> . 2007</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312162536.html">K488合金铝及钴铝渗层的结构与高温氧化和热腐蚀行为</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李玉春&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李玉春</a> <span> . 2009</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120111993406.html">一种铁钴钽合金粉的制备方法、铁钴钽合金粉及用途</a> <b>[P]</b> . <span> 中国专利： CN111957982A </span> <span> . 2020-11-20</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120110473873.html">铁钴钽合金溅射靶材的制备方法、铁钴钽合金溅射靶材及应用</a> <b>[P]</b> . <span> 中国专利： CN108004515A </span> <span> . 2018-05-08</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130453330516.html">High-strength thin plate of iron-nickel-cobalt alloy excellent in corrosion resisitance, repeated bending behavior and etchability, and production thereof</a> <b>[P]</b> . <span> 外国专利：  US5792286A </span> <span> . 1998-08-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有优异的耐蚀性，反复弯曲性能和孵化能力的铁镍钴合金高强度薄板及其生产 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130461686959.html">HIGH-STRENGTH THIN PLATE OF IRON-NICKEL-COBALT ALLOY EXCELLENT IN CORROSION RESISTANCE, REPEATED BENDING BEHAVIOR AND ETCHABILITY, AND PRODUCTION THEREOF</a> <b>[P]</b> . <span> 外国专利：  WO9312263A1 </span> <span> . 1993-06-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：高强度的镍钴钴合金薄板具有优异的耐腐蚀性能，重复的弯曲性能和可塑性以及其生产性能 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130409273893.html">Solid solution with unlimited range of solubility of components in the two-component system of vanadates (V) cobalt (II) and iron (III) as well as magnesium and iron (III) and methods for the production of solid solution with unlimited range of solubility of components in the two-component system of vanadates (V) cobalt (II) and iron (III) as well as magnesium and iron (III)</a> <b>[P]</b> . <span> 外国专利：  PL225790B1 </span> <span> . 2017-05-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在钒酸盐（V）钴（II）和铁（III）以及镁和铁（III）的二元体系中组分的溶解度不受限制的固溶体以及制备方法组分在钒酸盐（V）钴（II）和铁（III）以及镁和铁（III）的两组分体系中的溶解度 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: 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