Equilibrium adsorption of ethyl mercaptan and thiophene using molecular sieve 13X

摘要

In the present study, adsorption of the sulfur compound onto two types of molecular sieve (HYD1OB and LQ-MS-13X) in a batch system was investigated. It has been illustrated that HYD10B type has more adsorption capacity than LQ-MS-13X type to separate ethyl mercaptan from simulated liquid mixture. Selected as the better adsorbent the isotherm equilibrium adsorptions of ethyl mercaptan and thiophene in liquid phase had been carried out by using this type of molecular sieve in the temperature range of 25-65 degrees C. HYD10B-MS-13X brought out the highest adsorption capacity for adsorption of ethyl mercaptan component Diminution of adsorption capacity with temperature increment has been found and it was shown that adsorption of ethyl mercaptan is less affected by temperature changes. Using four more common isotherm models (Langmuir, Freundlich, Tempkin and Dubinin-Radushkevich), Freundlich isotherm was found to be the best representative model for describing ethyl mercaptan and thiophene equilibrium data. (C) 2017 Elsevier B.V. All rights reserved.