Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl]phenyl)-3-(dimethylamino)prop-2-en-l-one

Stability Nongrum; Susma Das; Shikpika Khanikar

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Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl]phenyl)-3-(dimethylamino)prop-2-en-l-one

机译：1-（3,5-双（三氟甲基]苯基）-3-（二甲基氨基）PR-2-en-L-1的合成，结构阐明和X射线晶体研究

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摘要

A new enaminone was synthesized by reacting 3,5-bis-[trifluoromethyl)acetophenones and N,N-dimethylformamide dimethyl acetal and its detailed structural and crystalline properties were studied. The crystal data were found to be as C13H11F6NO, monoclinic, space group P21/c (no. 14), a = 8.1556(8) A,b = 24.877(3) A, c = 7.6067(7) A, B = 116.745(6)°, V= 1378.2(3) A3, Z= 4, T= 293(2) K, u(MoKa) = 0.150 mmi, Dcalc= 1.500 g/cm3, 40777 reflections measured (5.594° < 26 < 56.786°), 3413 unique (Rint = 0.1040, Rsigma = 0.0584) which were used in all calculations. The final Ri was 0.0771 (I >2cr(I)) and wR2 was 0.2541 (all data).

机译：通过反应3,5-双甲基）苯乙酮和N，N-二甲基甲酰胺二甲基缩醛和其详细的结构和结晶性能来合成新的烯喃酮。发现晶体数据是C13H11F6NO，单岩，空间组P21 / C（NO.14），A = 8.1556（8）A，B = 24.877（3）A，C = 7.6067（7）A，B = 116.745 （6）°，v = 1378.2（3）A3，Z = 4，T = 293（2）k，U（Moka）= 0.150mmi，Dcalc = 1.500g / cm3，测量40777反射（5.594°<26 <56.786 °），3413独特（RINT = 0.1040，RSIGMA = 0.0584），用于所有计算。最终的RI为0.0771（I> 2CR（I））和WR2为0.2541（所有数据）。

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《European Journal of Chemistry》 |2019年第4期|共5页
作者
Stability Nongrum; Susma Das; Shikpika Khanikar;
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作者单位

Organic Research Laboratory Department of Chemical Science Assam Don Bosco University Tapesia Gardens Kamarkuchi Sonapur 782 402 Assam India;

Organic Research Laboratory Department of Chemical Science Assam Don Bosco University Tapesia Gardens Kamarkuchi Sonapur 782 402 Assam India;

Organic Research Laboratory Department of Chemical Science Assam Don Bosco University Tapesia Gardens Kamarkuchi Sonapur 782 402 Assam India;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Enaminones; Acetophenone; Trifluoromethyl; X-ray crystallography; Geometric parameters; N; N-Dimethylformamide dimethyl acetal;

机译：珐琅;苯酮;三氟甲基;X射线晶体学;几何参数;n;N-二甲基甲酰胺二甲基缩醛;

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机译：1-（3,5-双（三氟甲基]苯基）-3-（二甲基氨基）PR-2-en-L-1的合成，结构阐明和X射线晶体研究
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7. Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl)phenyl)-3-(dimethylamino)prop-2-en-1-one [O] . Stability Nongrum, Susma Das, Shikpika Khanikar, 2019

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机译：在公司制造或加工的化学混合物中，使用2-丙醇，1-（双（3-（二甲基氨基）丙基）氨基）吸收潜在吸入后财产所有者所指称的健康影响摘要; 1,3-丙二胺，N1-（3-（二甲基氨基）丙基）-N1，N3，N3-三甲基; 1H-咪唑，1,2-二甲基; 1,2-二氯乙烯; 1,1,1,3,3-五氟丙烷; 2-丁氧基乙醇。

Synthesis, structural elucidation and X-ray crystallographic studies of 1-(3,5-bis(trifluoromethyl]phenyl)-3-(dimethylamino)prop-2-en-l-one

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