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Melt-State Viscoelastic Properties of POSS-Containing Polyethylene Nanocomposites

机译:含POSS的聚乙烯纳米复合材料的熔融态粘弹性质

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摘要

This article reports on the melt-state viscoelastic properties of polyhedral oligomeric silsesquioxane (POSS)-containing linear low-density polyethylene (LLDPE) composites. LLDPE nanocomposites with three different weight percentages of POSS were prepared via melt-mixing at 150℃. The melt-state rheological behaviour of pure LLDPE and various nanocomposite samples were studied by stress/strain control rheometry in the linear viscoelastic region and the results show that POSS particles play the role of a lubricant by decreasing the viscoelastic properties of LLDPE. The mechanical properties exhibited a decrease with increasing POSS content in the LLDPE matrix.
机译:本文报道了含多面体低聚倍半硅氧烷(POSS)的线性低密度聚乙烯(LLDPE)复合材料的熔融态粘弹性。通过150℃熔融混合制备了三种不同POSS含量的LLDPE纳米复合材料。通过应力/应变控制流变学研究了线性线性粘弹性区中纯LLDPE和各种纳米复合材料样品的熔体流变行为,结果表明POSS颗粒通过降低LLDPE的粘弹性而起到润滑剂的作用。随着LLDPE基质中POSS含量的增加,机械性能降低。

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