Corn oil based poly(urethane-ether-amide)/fumed silica nanocomposite coatings for anticorrosion application

摘要

Poly(urethane-ether-amide) (PUIEtA) nanocomposite coatings on mild steel were prepared by using corn oil, isosorbide and isophorone diisocynate and fumed silica. The syntheses steps were confirmed by FTIR, H-1 NMR and C-13 NMR spectroscopy techniques. The morphology of PUIEtA nanocomposite coating was studied by SEM-EDX, that confirmed the presence of nanosilica and thermal behavior was studied by DSC/TGA analysis. The anticorrosion performance of PUIEtA coating systems on mild steel, exposed to 3.5wt% NaCl solution, was evaluated using electrochemical impedance spectroscopy. Scratch hardness, pencil hardness, adhesion, and bending test were performed in order to investigate the performance of nanocomposite coating on mild steel substrate. It was found that PUIEtA-fumed silica nanocomposite coating could provide much better protection than PUIEtA. PUIEtA-3 nanocomposite coating can be safely used up to 200 degrees C.