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The THz Spectrum of Density Fluctuations of Water: The Viscoelastic Regime

机译:水的密度波动的太赫兹频谱:粘弹性体系

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摘要

Relevant advances in the knowledge of the water dynamics at mesoscopic scales are reviewed, while mainly focusing on the contribution provided by high resolution inelastic X-ray scattering (IXS). In particular it is discussed how the use of IXS has improved our understanding of viscoelastic properties of water at THz frequencies. This specifically involves some solid-like features such as the onset of shear wave propagation, a sound velocity surprisingly similar to the one of ice, and an anomalously low sound absorption coefficient. All these properties can be explained by assuming the coupling of THz density fluctuations with a structural relaxation process connected to the breaking and forming of hydrogen bonds (HBs). This review also includes more recent IXS results demonstrating that, upon approaching supercritical conditions, relaxation phenomena in water gradually lose their structural character becoming essentially collisional in character. Furthermore, GHz spectroscopy results on supercooled water, suggesting the occurrence of a structural arrest, are discussed. An overview of the new opportunities offered by next generation IXS spectrometers finally concludes this review.
机译:本文对介观尺度的水动力学知识的相关进展进行了回顾,同时主要关注高分辨率非弹性X射线散射(IXS)的贡献。尤其要讨论的是,IXS的使用如何改善了我们对THz频率下水的粘弹性质的理解。具体来说,这涉及到一些类似固体的特征,例如剪切波传播的开始,惊人的类似于冰的声速以及异常低的吸声系数。所有这些特性都可以通过假设THz密度波动与与氢键(HBs)的断裂和形成有关的结构弛豫过程的耦合来解释。这篇综述还包括最新的IXS结果,表明在接近超临界条件时,水中的松弛现象逐渐失去其结构特征,从而本质上具有碰撞性。此外,讨论了过冷水的GHz光谱结果,表明发生了结构性阻滞。总结了下一代IXS光谱仪提供的新机会。

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