Kinetic study of the reaction of nucleophilic cyclopropanation of C60 fullerene with halogenated maleopimarimide

Biglova Yulya N.; Malikova Rauilya N.; Petrova Svetlana F.; Ivanov Sergey P.; Sakhautdinov Ilshat M.; Mustafin Akhat G.

摘要

Abstract >The kinetics of nucleophilic fullerene cyclopropanation by halomethyl ketones with a diterpene fragment has been studied by the Bingel method, and the influence of the biologically active cyclopropanating agent on the process has been estimated. It has been revealed that favorable conditions for carrying out the reaction result in maximum monofunctionalized methanofullerenes formation with the maximum yield. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 通过烘干方法研究了卤代甲基酮与二萜片段的富勒烯环丙酮的动力学，并估计了生物活性环丙酮对该方法的影响。据揭示，进行反应的有利条件导致最大产率的最大单官能化甲基汞。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-20953/'>《International Journal of Chemical Kinetics》</a> <b style="margin: 0 2px;">|</b><span>2019年第5期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Biglova Yulya N.&option=202" target="_blank" rel="nofollow">Biglova Yulya N.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Malikova Rauilya N.&option=202" target="_blank" rel="nofollow">Malikova Rauilya N.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Petrova Svetlana F.&option=202" target="_blank" rel="nofollow">Petrova Svetlana F.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ivanov Sergey P.&option=202" target="_blank" rel="nofollow">Ivanov Sergey P.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sakhautdinov Ilshat M.&option=202" target="_blank" rel="nofollow">Sakhautdinov Ilshat M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mustafin Akhat G.&option=202" target="_blank" rel="nofollow">Mustafin Akhat G.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryBashkir State UniversityUfa Russian Federation;</p> <p>Ufa Institute of ChemistryRussian Academy of Sciences450054 Ufa Russian Federation;</p> <p>Ufa Institute of ChemistryRussian Academy of Sciences450054 Ufa Russian Federation;</p> <p>Ufa Institute of ChemistryRussian Academy of Sciences450054 Ufa Russian Federation;</p> <p>Ufa Institute of ChemistryRussian Academy of Sciences450054 Ufa Russian Federation;</p> <p>Department of ChemistryBashkir State UniversityUfa Russian Federation;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=60 fullerene&option=203" rel="nofollow">60 fullerene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bingel 2 + 1‐cycloaddition&option=203" rel="nofollow">Bingel 2 + 1‐cycloaddition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=kinetic elucidation&option=203" rel="nofollow">kinetic elucidation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=methyl maleopimarate&option=203" rel="nofollow">methyl maleopimarate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rosin&option=203" rel="nofollow">rosin;</a> </p> <div class="translation"> 机译：[60]富勒烯;Bingel [2 + 1] -cycloaddition;动力学阐明;甲基甲基甲基甲基; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022992140.html">Kinetic study of the reaction of nucleophilic cyclopropanation of C60 fullerene with halogenated maleopimarimide</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Biglova Yulya N.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Biglova Yulya N.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Malikova Rauilya N.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Malikova Rauilya N.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Petrova Svetlana F.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Petrova Svetlana F.,</a> <a href="/journal-foreign-20953/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Journal of Chemical Kinetics .</a> <span>2019</span><span>,第5期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：C60富勒烯与卤代马达莫西米甲醚的亲核环丙烷反应的动力学研究</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704011631757.html">An ab Initio Study of the Kinetics of the Reactions of Halomethanes with the Hydroxyl Radical. 2. 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨作银&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨作银</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张敬畅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张敬畅</a> <span> <a href="/journal-cn-53859/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学学报 </a> </span> <span> . 2008</span><span>,第007期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_new-carbon-materials_thesis/0201249033033.html">富勒烯(C60)在氩中的反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李润明&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李润明</a> <span> <a href="/journal-cn-9245/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 新型炭材料 </a> </span> <span> . 1992</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-29995_thesis/020222300585.html">环庚三烯配体在异核双金属羰基络合物与芳基锂试剂反应中的新奇亲核加成和开环反应</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖努&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 肖努</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张庶&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张庶</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邱志雷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邱志雷</a> <span> <a href="/conference-cn-29995/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十二届全国金属有机化学会议 </a> <span> <span> . 2002</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031646758.html">[60]富勒烯的亲核环加成反应研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李家星&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李家星</a> <span> . 2008</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204559526.html">一种富勒烯C60纳米晶体联合CaMKII抑制剂的组合物的应用</a> <b>[P]</b> . <span> 中国专利： CN108904532B </span> <span> . 2021.07.27</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120112257184.html">富勒烯C60的配料及其制备方法</a> <b>[P]</b> . <span> 中国专利： CN112265980A </span> <span> . 2021-01-26</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130457557945.html">METHOD FOR EFFICIENTLY AND SELECTIVELY SEPARATING AND PURIFYING FULLERENE C60 BY PRELIMINARILY SEPARATELY TREATING COMPONENT H OR COMPONENT B IN PETROLEUM PITCH COMPOSITION AS RAW MATERIALS, SEPARATELY EXTRACTING TREATED COMPONENTS WITH SOLVENTS, RESPECTIVELY, SUBJECTING EXTRACTS TO HEATING AND PRESSURIZING TREATMENT TO PRODUCE BAKED PITCH CONTAINING FULLERENE C60, EXTRACTING FULLERENE C60 WITH SPECIAL SOLVENT, AND THEN POURING EXTRACT SOLUTION INTO SILICA GEL-PACKED LAYER</a> <b>[P]</b> . <span> 外国专利：  JPH082909A </span> <span> . 1996-01-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过在石油沥青组合物中作为原料直接分离处理H或B成分的方法，选择性地分离和纯化富勒烯C60的方法，分别从各个方面对化合物的含量和含量进行了适当的选择，所涉及的内容包括多个，用特殊溶剂萃取富勒烯C60，然后将萃取液倒入硅胶凝胶层中 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130449246978.html">C60 FULLERENE MOLECULAR DERIVATIVE AND SYNTHESIS OF C60 FULLERENE MOLECULAR DERIVATIVE</a> <b>[P]</b> . <span> 外国专利：  JP2000344764A </span> <span> . 2000-12-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：C60富勒烯分子衍生物和C60富勒烯分子衍生物的合成 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130439884953.html">Modification of nucleophilic proteins used in construction of e.g. enzymatic biosensors, by chemical reaction between nucleophilic groups free of protein residuals and halogenated derivatives, while controlling characteristics of proteins</a> <b>[P]</b> . <span> 外国专利：  ES2242456A1 </span> <span> . 2005-11-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：修饰用于构建例如核糖核酸的亲核蛋白酶促生物传感器，通过无蛋白质残基的亲核基团与卤代衍生物之间的化学反应，同时控制蛋白质的特性 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img 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