Preparation of microencapsulated powders by an aerosol spray method and their optical properties

摘要

Microencapsulated powders were prepared by an aerosol spray method using a precursor comprised of a mixture of two types of sols as well as a sol-aqueous mixture precursor solution. Two different types of sols were used as precursors to prepare microencapsulated small-SiO_2/large-SiO_2 and Al_2O_3/SiO_2 powders. A microencapsulated ZrO_2/SiO_2 powder was also prepared from a mixture of SiO_2 sol and an aqueous precursor solution of zirconyl nitrate dihydrate. For preparing small-SiO_2/large-SiO_2 powders, two different sizes, i.e. 6 and 109 nm, of SiO_2 sols were used as precursors. The results show that the larger SiO_2 particles ere encapsulated with the smaller ones. A similar result was also observed in the preparation of an Al_2O_3/SiO_2 powder prepared from a mixture of Al_2O_3 (18 nm) and a SiO_2 (109 nm) sol precursor. The Al_2O_3 particles appeared on the surface of the prepared powder. In the case of the ZrO_2/SiO_2 shell. The effect of precursor ratios n the morphology of powders was also investigated. The light scattering characteristics of the prepared particles were also investigated using a laser particle counter coupled with a pulse height analyzer. The effective refractive indices of the microencapsulated powders varied considerably with the content of coating material.