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Characteristics of the Thermal Desorption and Conversion of Organic Templates in Micropores of Zeolite-like Phosphates

机译:沸石状磷酸盐微孔中有机模板的热脱附和转化特征

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摘要

The characteristics of the dehydration, thermal desorption and thermal decomposition of organic templates in zeolite-like aluminophosphates and silica aluminophosphates of different structural types have been elucidated. The influence of the pore size and acidic centres on the composition of the thermal decomposition products, including the secondary syntheses of normal, cyclic and aromatic hydrocarbons, has been stablished. The possibility of dehydration, oligomerization, cyclization, cracking, aromatization and alkylation of hydrocarbons in zeolite-like phosphates has been shown.
机译:已经阐明了不同结构类型的沸石状铝磷酸盐和二氧化硅铝磷酸盐中有机模板的脱水,热脱附和热分解的特征。已经确定了孔径和酸性中心对热分解产物组成的影响,包括正构,环状和芳族烃的二次合成。已经显示出沸石样磷酸盐中烃的脱水,低聚,环化,裂化,芳构化和烷基化的可能性。

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