Carbon‐Support‐Based Heterogeneous Nanocatalysts: Synthesis and Applications in Organic Reactions

Bahuguna Ashish; Kumar Ajay; Krishnan Venkata

摘要

Abstract >Carbon‐based‐materials, owing to their wide availability and low cost, have been utilized for a variety of applications including heterogeneous catalysis. Various carbonaceous materials have been used as supports for transition metals or other materials. These support materials have shown their potential for development of green and sustainable approaches to heterogeneous catalysis. In this review, we discuss the utilization of carbon‐based materials as supports for heterogeneous catalysts, especially in organic transformations. We have focused our discussions predominantly on four categories of carbonaceous supports, namely graphene (including, graphene oxide (GO) and reduced graphene oxide (RGO)), graphitic carbon nitride (GCN), carbon nanotubes (CNT) and activated carbon (AC) for various organic transformation reactions. Several approaches for the synthesis of these materials along with their application as heterogeneous catalysts for organic transformation reactions have been elaborated in detail. In addition, different aspects of organic synthesis, including hydrogenation, oxidation, reduction, condensation, and multi‐component reactions, catalyzed by these materials have been discussed. Furthermore, organic transformations leading to the sustainable synthesis of valuable products from biomass have also been discussed. Finally, after a brief summary, the future perspectives of this very interesting class of materials are provided. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 由于其宽的可用性和低成本，碳基材料已被用于各种应用，包括异质催化。各种碳质材料已被用作过渡金属或其他材料的支撑。这些支持材料表明了它们对异质催化的绿色和可持续方法的发展潜力。在本文中，我们讨论了碳基材料的利用作为非均相催化剂的支持，特别是在有机转化中。我们主要专注于我们的讨论，主要是四类碳质载体，即石墨烯（包括石墨烯氧化物（GO）和氧化石墨烯（RGO），石墨碳氮化物（GCN），碳纳米管（CNT）和活性炭（AC）对于各种有机转化反应。详细阐述了几种用于合成这些材料的方法以及它们作为有机转化反应的异质催化剂的应用。另外，已经讨论了这些材料催化的有机合成的不同方面，包括氢化，氧化，还原，缩合和多组分反应。此外，还讨论了导致来自生物质的可持续合成宝贵产品的有机转化。最后，在简要摘要之后，提供了这种非常有趣的材料类别的未来观点。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19765/'>《Asian Journal of Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第8期</span><b style="margin: 0 2px;">|</b><span>共43页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bahuguna Ashish&option=202" target="_blank" rel="nofollow">Bahuguna Ashish;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kumar Ajay&option=202" target="_blank" rel="nofollow">Kumar Ajay;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Krishnan Venkata&option=202" target="_blank" rel="nofollow">Krishnan Venkata;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Indian Institute of Technology Mandi KamandSchool of Basic Sciences and Advanced Materials Research CenterHimachal Pradesh 175005 India;</p> <p>Indian Institute of Technology Mandi KamandSchool of Basic Sciences and Advanced Materials Research CenterHimachal Pradesh 175005 India;</p> <p>Indian Institute of Technology Mandi KamandSchool of Basic Sciences and Advanced Materials Research CenterHimachal Pradesh 175005 India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1184.html" title="有机化学">有机化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=heterogeneous catalysis&option=203" rel="nofollow">heterogeneous catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphene&option=203" rel="nofollow">graphene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphitic carbon nitride&option=203" rel="nofollow">graphitic carbon nitride;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon nanotubes&option=203" rel="nofollow">carbon nanotubes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=activated carbon&option=203" rel="nofollow">activated carbon;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sustainable chemistry&option=203" rel="nofollow">sustainable chemistry;</a> </p> <div class="translation"> 机译：异质催化;石墨烯;石墨碳氮化物;碳纳米管;活性炭;可持续化学; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div 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<b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵惠忠&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵惠忠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李轩科&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李轩科</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=计道珺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,计道珺</a> <span> <a href="/conference-cn-31691/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 全国第二届纳米材料和技术应用会议 </a> <span> <span> . 2001</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314310762.html">纳米多级结构催化剂的组装合成及其应用于清洁有机反应的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=魏永懿&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 魏永懿</a> <span> . 2012</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120106517742.html">一种合成气合成高碳醇的Cu-Fe基催化剂及其制备方法和其在合成气合成高碳醇工艺中的应用</a> <b>[P]</b> . <span> 中国专利： CN102319575A </span> <span> . 2012-01-18</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120102250076.html">异质原子杂化介孔碳负载钴基费托合成催化剂及制法和应用</a> <b>[P]</b> . <span> 中国专利： CN103691468A </span> <span> . 2014-04-02</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130414101533.html">MANUFACTURING METHOD OF EGG-SHELL TYPE COBALT/SILICA NANOCATALYSTS FOR FISCHER-TROPSCH SYNTHESIS REACTION AND COBALT/SILICA NANOCATALYSTS THEREOF, MANUFACTURING METHOD OF LIQUID HYDROCARBON USING THE SAME</a> <b>[P]</b> . <span> 外国专利：  KR101524574B1 </span> <span> . 2015-06-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: 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