Resin-supported palladium nanoparticles as recyclable catalyst for the hydrodechlorination of chloroarenes and polychlorinated biphenyls

摘要

This study focuses on the hydrodechlorination of chlorinated arenes as well as polychlorinated biphenyls (PCBs) utilizing a resin-supported Pd(0) catalyst. Bearing in mind the dangers associated with toxic PCBs, treatment of the remnants of industrial wastes containing PCB congeners is indispensable. One such method is reductive hydrodechlorination. Instead of utilizing traditional sources of hydrogen, ammonium formate is used for in situ hydrogen generation. Moreover, palladium nanoparticles are supported on an anionic exchange resin which makes the process recyclable with a negligible change of yield after recycling experiments. The catalyst is demonstrated in the hydrodechlorination of a wide range of chlorinated compounds and PCB congeners including aroclors 1242, 1248 and 1254. Copyright (C) 2016 John Wiley & Sons, Ltd.