Optical properties and optimized conditions for polymer dispersed liquid crystal containing UV curable polymer and nematic liquid crystal

摘要

Polymer dispersed liquid crystal was synthesized by combining a UV curable polymer and a nematic liquid crystal. Optimized conditions for the optical properties of the PDLC were found to be the concentration ratio of LC and polymer at 7:3, UV curing time of 18 min, and the thickness less than 25 mm. In the case of the high LC concentration (>= 70%) sample, the amount of liquid crystal segregated in the polymerization process was enough to form a spherical shape of droplet, and the threshold driving voltage was reduced. The response time for the turn-on process was nearly independent of the concentration, while the turn-off process was almost proportional to the concentration. From microscopic image and UV-visible spectrum analysis, the relation between LC droplet morphology and optical properties were explained. (C) 2014 Elsevier B.V. All rights reserved.