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Torlon? hollow fiber membranes for organic solvent reverse osmosis separation of complex aromatic hydrocarbon mixtures

机译：Torlon？用于有机溶剂的中空纤维膜，复合芳烃混合物的有机溶剂反渗透分离

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Abstract > Defect‐free polyamide‐imide (Torlon?) hollow fiber membranes were fabricated to investigate the potential for polymer‐based organic solvent reverse osmosis (OSRO) separations. The quality of the membranes was assessed by gas permeation, and the membranes were found to be defect‐free. Low molecular weight cut‐offs of ~180?g/mol were obtained using a complex mixture of aromatic hydrocarbons relevant to refinery separations. We demonstrate bulk OSRO‐type separations of 80/20 (mol%) mixtures of toluene and 1,3,5‐triisopropylbenzene (TIPB, 204?g/mol). At an upstream pressure of 80–90?bar, we find that the permeate concentration was approximately 98.5–99.0 mol% toluene and that the TIPB rejection coefficient was approximately 90% in the permeate. We observed low solvent permeances of 0.01?L/m 2 hr?bar, which can be attributed to the low OSRO driving forces and the low permeability of Torlon?. The membranes were found to provide stable performance up to pressures of 95?bar and temperatures of 60°C. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 无缺陷的聚酰胺 - 酰亚胺（Torlon？）中空纤维膜被制造成研究聚合物基有机溶剂反渗透（OSO）分离的可能性。通过气体渗透评估膜的质量，发现膜被无缺陷。利用与炼油厂分离相关的芳烃混合物，获得低分子量截止〜180·克/摩尔。我们证明了甲苯和1,3,5-三异丙基苯的80/20（摩尔％）混合物的散装Osro型分离（Tipb，204 ~g / mol）。在80-90的上游压力下，我们发现渗透物浓度约为98.5-99.0mol％甲苯，并且渗透物抑制系数约为90％。我们观察到0.01的低溶剂渗透渗透剂 2 </ sup> HR？吧，可归因于低OSO驱动力和Torlon的低渗透率？发现膜可提供稳定的性能，高达95°C的压力和60℃的温度。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18537/'>《AIChE Journal》</a> <b style="margin: 0 2px;">|</b><span>2019年第12期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jang Hye‐Youn&option=202" target="_blank" rel="nofollow">Jang Hye‐Youn;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Johnson J. R.&option=202" target="_blank" rel="nofollow">Johnson J. R.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ma Yao&option=202" target="_blank" rel="nofollow">Ma Yao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mathias Ronita&option=202" target="_blank" rel="nofollow">Mathias Ronita;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bhandari Dhaval A.&option=202" target="_blank" rel="nofollow">Bhandari Dhaval A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lively Ryan P.&option=202" target="_blank" rel="nofollow">Lively Ryan P.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Chemical &</p> <p>Biomolecular EngineeringGeorgia Institute of TechnologyAtlanta Georgia;</p> <p>Corporate Strategic ResearchExxonMobil Research &</p> <p>EngineeringAnnandale New Jersey;</p> <p>School of Chemical &</p> <p>Biomolecular EngineeringGeorgia Institute of TechnologyAtlanta Georgia;</p> <p>School of Chemical &</p> <p>Biomolecular EngineeringGeorgia Institute of TechnologyAtlanta Georgia;</p> <p>Corporate Strategic ResearchExxonMobil Research &</p> <p>EngineeringAnnandale New Jersey;</p> <p>School of Chemical &</p> <p>Biomolecular EngineeringGeorgia Institute of TechnologyAtlanta Georgia;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/238.html" title="化学工业">化学工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=aromatics&option=203" rel="nofollow">aromatics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fractionation&option=203" rel="nofollow">fractionation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hollow fiber membranes&option=203" rel="nofollow">hollow fiber membranes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organic solvent reverse osmosis&option=203" rel="nofollow">organic solvent reverse osmosis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Torlon?&option=203" rel="nofollow">Torlon?;</a> </p> <div class="translation"> 机译：芳族;分馏;中空纤维膜;有机溶剂反渗透;Torlon？; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022505848.html">Torlon? hollow fiber membranes for organic solvent reverse osmosis separation of complex aromatic hydrocarbon mixtures</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jang Hye‐Youn&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jang Hye‐Youn,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Johnson J. 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href="/academic-journal-cn_journal-functional-polymers_thesis/0201232647318.html">水热处理Silicalite-Ⅰ沸石填充硅橡胶膜Ⅰ对有机溶剂—水混合物的渗透蒸发分离性质</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈新&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈新</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=平郑骅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,平郑骅</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张耀华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张耀华</a> <span> <a href="/journal-cn-11101/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 功能高分子学报 </a> </span> <span> . 1994</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296696843.html">中空纤维复合膜用于回收有机溶剂蒸气的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王东亮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王东亮</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=尹桂林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,尹桂林</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马庙江&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,马庙江</a> <span> <a href="/journal-cn-56690/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 环境科学 </a> </span> <span> . 1991</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_polymer-materials_thesis/0201264255201.html">国外反渗透,超滤和微过滤用于分离液体混合物的现况</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=戚文定&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 戚文定</a> <span> <a href="/journal-cn-42177/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子材料 </a> </span> <span> . 1990</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-32017_thesis/02022494977.html">用于有机溶剂分离的高性能膜分离材料设计</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王保国&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王保国</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=山口猛央&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,山口猛央</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=中尾真一&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,中尾真一</a> <span> <a href="/conference-cn-32017/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2000年全国高分子材料工程应用研讨会 </a> <span> <span> . 2000</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031149109.html">部分有机溶剂、离子液体及其混合物对青海弧菌Q67的毒性效应</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘芳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘芳</a> <span> . 2007</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120105241547.html">通过将盐溶解于有机溶剂并除去该溶剂来制备无定形阿托伐他汀半钙的方法，所述有机溶剂为醇和酮和 /或酯的混合物</a> <b>[P]</b> . <span> 中国专利： CN101039906A </span> <span> . 2007-09-19</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105233622.html">在包含有机溶剂和水的两相混合物中用元素卤素对萘嵌苯甲酰亚胺卤化，其中从有机溶剂中连续除去所形成的卤化氢</a> <b>[P]</b> . <span> 中国专利： CN101035788A </span> <span> . 2007-09-12</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130419412224.html">METHOD FOR CONCENTRATING AND SEPARATING ORGANIC SOLVENT IN INDUSTRIAL WASTE WATER BY A MEMBRANE MODULE USING POLYAMIDE-BASED REVERSE OSMOSIS SEPARATION MEMBRANE</a> <b>[P]</b> . <span> 外国专利：  KR20130101280A </span> <span> . 2013-09-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：聚酰胺基反渗透分离膜的膜组件富集分离工业废水中有机溶剂的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130443702978.html">Sulfonation of aromatic polyether sulfones in a halogenated hydrocarbon and a strongly polar organic solvent useful for preparation of coatings, shaped bodies, films, membranes, e.g. cation exchange membranes, or fibers</a> <b>[P]</b> . <span> 外国专利：  DE10149034A1 </span> <span> . 2003-05-08</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：芳族聚醚砜在卤代烃和强极性有机溶剂中的磺化可用于制备涂料，成型体，薄膜，膜，例如阳离子交换膜或纤维 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130457415680.html">INTERFACIALLY POLYMERIZED MEMBRANES FOR THE REVERSE OSMOSIS SEPARATION OF ORGANIC SOLVENT SOLUTIONS.</a> <b>[P]</b> . <span> 外国专利：  MY107411A </span> <span> . 1995-12-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：反向聚合分离有机溶剂溶液的界面聚合膜。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" 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