Cyclic Water Hexamers and Decamers in a Porous Lanthanide-Organic Framework: Correlation between Some Physical Properties and Crysal Structure

摘要

Erbium fumarate [Er_2(fum)_3(H_2O)_4]·8H_2O, 1, (fum = fumarate dianion) crystallizes at room temperature in a silica gel column. The structure is three-dimensional and consists of layers of erbium fumarate pillared by fumarate dianions acting in the bis-chelating mode. The layers contain arrays of erbium cations bridged by fumarate dianions acting in the bis-bidentate bridging mode. The relatively large channels formed in the direction of the a and c axes are filled by water molecules that form a hydrogen bonded layer, comprising cyclic hexamers with both boat and chair conformations and cyclic decamers with boat-chair-boat conformation. The water molecules are reversibly removed at 90 ℃. The evacuated metal-organic framework, 2, is stable up to 400 ℃. Both compounds 1 and 2 exhibit weak antiferromagnetic interactions.