A Novel Pillar-Layered Organic-Inorganic Hybrid Based on Lanthanide Polymer and Polyomolybdate Clusters:New Opportunity toward the Design and Synthesis of Porous Framework

摘要

An unprecedented microporous lanthanum polymolybdate,[{La(H_2O)_5(dipic)}{La(H_2O)(dipic)}]_2{Mo_8O_(26)}centre dot l0H_2O (H_2dipic = pyridine-2,6-dicarboxylic acid) 1,which is constructed from lanthanum-organic coordination polymer sheets pillared by individual octamolybdate clusters,is reported.