Novel Two-Dimensional Network Constructed from Polyoxomolybdate Chains Linked through Copper-Organonitrogen Coordination Polymer Chains:Hydrothermal Synthesis and Structure of [H_2bpy][Cu(4,4'-bpy)]_2[HPCuMo_(11)O_(39)]

摘要

A novel compound,[H_2bpy][Cu(4,4'-bpy)]_2[HPCuMo_(11)O_(39)] (1),has been prepared under mild hydro-thermal conditions and has been structurally characterized by single-crystal X-ray diffraction.Compound 1 exhibits a novel two-dimensional network constructed from the interconnecting of polyoxomolybdate chains,{HPCuMo_(11)O_(39)}_n~(4n-),and transition metal coordination polymer chains,{Cu(4,4'-bpy)}_n~(n+).It is the first example of a two-dimensional structure formed by a polyoxomolybdate chain through the linkage of a transition metal coordination polymer chain.