A novel three-dimensional SrII coordination polymer based on benzene-1,2,4,5-tetracarboxylate: hydrothermal synthesis, crystal structure and spectroscopic and thermal studies

摘要

Coordination of the anions of benzenecarboxylic acids with metal cations leads to coordination polymers with various structural features. Very few examples of strontium-based structures have been reported. A new three-dimensional coordination polymer, namely poly[aqua(mu_12-benzene-1,2,4,5-tetracarboxylato)-distrontium(II)], [Sr_2(C_10H_2O_8)(H_2O)]_n, has been synthesized under hydro-thermal conditions and characterized by thermal analysis, vibrational spectro-scopy (Raman and IR), single-crystal X-ray diffraction and powder X-ray diffraction. The coordination geometries around the two independent SrII ions can be described as a distorted dodecahedron and a distorted monocapped square antiprism. The compound features a three-dimensional structure containing inorganic motifs, with two-dimensional layers connected through organic linkers, and possesses a topologic structure of a binodal (6,12) connected alb net with the Schlafli symbol {4~15}_2{4~48.6~18}. The final product of thermal decomposition is strontium oxide (SrO).