Crystal growth, structure and characterization of Er_6B_4O_(15) as self-activated eye-safe laser material within the near-infrared waveband

摘要

A new rare-earth borate Er_6B_4O_(15) was synthesized by a solid-state reaction technique. The crystal was obtained by a flux method. Single-crystal X-ray diffraction analysis revealed that the crystal structure is composed of ErO_6 polyhedra sharing edges and BO_3 groups. The absorption, near-infrared fluorescence spectra and the fluorescence decay curve of Er: ~4I_(13/2) energy level in the Er_6B_4O_(15) crystal were measured at room temperature. The absorption peak was located at 977 nm with absorption cross section of 1.16 × 10~(-21) cm~2 and a full width at half-maximum (FWHM) of 16 nm, which is very suitable for commercial 980 nm laser diode pumping. A maximum emission peak at 1560 mm with a broad FWHM of 64 nm was observed in this crystal because of the Er~(3+) transition ~4I_(13/2)→~4I_(15/2), while the emission cross section was calculated to be 8.53 × 10~(-20) cm~2. These results imply that the Er_6B_4O_(15) crystal is a promising candidate material for the achievement of an eye-safe near-infrared wavelength laser.