Determining modified reaction parameters for the real-time measurement of BTEX in biogas and nitrogen using Selected Ion Flow Tube Mass Spectrometry (SIFT-MS)

摘要

The increasing demand for high-quality biogas and the reduction of reliance on natural gas have driven the need for a well-defined framework to ensure conformity and quality of biogas by the introduction of traceable reference materials and methods across the community. Furthermore, there is a great need to quantify critical trace impurities in biogas. Here, we perform real-time measurements on reference gas standards containing trace hydrocarbons in biogas that are traceable to the international system of units using Selected Ion Flow Tube Mass Spectrometry (SIFT-MS). There are limited data on reaction rate constants in biogas matrices for SIFT-MS, and here we use the traceable gas standards to determine and compare the reaction rate constants of trace hydrocarbons in biogas and nitrogen. Here, we modify SIFT-MS constants for biogas avoiding the current 30 % bias and prevent the overestimation in the concentration of hydrocarbon amount fractions.