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Red Phosphorus Flags Lithium Dendrites

机译:红磷旗锂枝晶

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James Tour and his lab at Rice University have made battery cells with a coat of red phosphorus on the separator that keeps the anode and cathode electrodes apart. The phosphorus alerts management systems used to charge and monitor batteries by detecting the formation of lithium dendrites. Lithium metal anodes charge much faster and hold about 10 times more energy by volume than common lithium-ion anodes used in just about every electronic device on the market, including cellphones and electric cars, writes Phys.org. But charging lithium-infused anodes forms dendrites that, if they reach the cathode, cause a short circuit and possibly a fire or explosion. By using a red phosphorus-coated separator, the battery’s charging voltage changes when a dendrite reaches the separator. That tells the battery management system to stop charging.
机译:詹姆斯之旅和他在赖斯大学的实验室使电池单元在隔板上用一层红色磷,使阳极和阴极电极分开。 磷警报用于通过检测锂枝晶的形成来充电和监控电池的管理系统。 锂金属阳极电荷更快,并且比仅在市场上的每个电子设备的常见锂离子阳极(包括手机和电动汽车)的常见锂离子阳极收取的能量比常见的锂离子阳极相当多约10倍。 但充电锂注入阳极形成枝形曲线,如果它们到达阴极,导致短路和可能是火灾或爆炸。 通过使用红色磷涂覆的分离器,电池的充电电压在枝晶到达隔板时会发生变化。 这告诉电池管理系统停止充电。

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