Thermo-responsive polymer brushes on glass plate prepared from a new class of amino acid-derived vinyl monomers and their applications in cell-sheet engineering

Nobuyuki Higashi; Ayaha Hirata; Shin-nosuke Nishimura; Tomoyuki Koga

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Thermo-responsive polymer brushes on glass plate prepared from a new class of amino acid-derived vinyl monomers and their applications in cell-sheet engineering

机译：玻璃板上的热响应聚合物刷，由新类氨基酸衍生的乙烯基单体及其在细胞片工程中的应用

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?Amino acid-based polymer brushes were prepared on glass plate by SI-ATRP.

?Brushes showed phase transitions from swollen to collapsed states.

?Transition temperature (TT) could be varied by adjusting the copolymer composition.

?Brushes aboveTTbehaved as effective support for cell adhesion without toxicity.

?Resultant cell-sheets were detached by cooling below the correspondingTTs.

Abstract

机译：<！[cdata [

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？通过Si-ATRP在玻璃板上制备氨基酸基聚合物刷。

？< / CE：标签> 画笔显示从肿胀到折叠状态的阶段转换。

？转变温度（ t ）可以改变”> t ）的柱。

？上面的画笔 t t 表现为对细胞粘附的有效支持，没有毒性。

？通过冷却分离所产生的细胞纸在相应的 t t s。

抽象< / CE：部分标题

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来源
《Colloids and Surfaces, B. Biointerfaces 》 |2017年第2017期| 共8页
作者
Nobuyuki Higashi; Ayaha Hirata; Shin-nosuke Nishimura; Tomoyuki Koga;
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作者单位

Department of Molecular Chemistry and Biochemistry Faculty of Science and Engineering Doshisha University;

Department of Molecular Chemistry and Biochemistry Faculty of Science and Engineering Doshisha University;

Department of Molecular Chemistry and Biochemistry Faculty of Science and Engineering Doshisha University;

Department of Molecular Chemistry and Biochemistry Faculty of Science and Engineering Doshisha University;

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原文格式 PDF
正文语种 eng
中图分类胶体化学（分散体系的物理化学） ;
关键词
Amino acid-derived vinyl polymer; Thermo-responsive polymer brush; Surface-initiated atom transfer radical polymerization; Collapse temperature (TT); Fibroblasts culture; Cell sheet engineering;

机译：氨基酸衍生的乙烯基聚合物;热响应性聚合物刷;表面引发的原子转移自由基聚合;塌陷温度（TT）;成纤维细胞培养;蜂窝板工程;

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1. Thermo-responsive polymer brushes on glass plate prepared from a new class of amino acid-derived vinyl monomers and their applications in cell-sheet engineering [J] . Nobuyuki Higashi, Ayaha Hirata, Shin-nosuke Nishimura, Colloids and Surfaces, B. Biointerfaces . 2017 ,第期

机译：玻璃板上的热响应聚合物刷，由新类氨基酸衍生的乙烯基单体及其在细胞片工程中的应用
2. Surface Modification of Halogenated Polymers. 10. Redox Catalysis Induction of the Polymerization of Vinylic Monomers. Application to the Localized Graft Copolymerization of Poly(tetrafluoroethylene) Surfaces by Vinylic Monomers [J] . Catherine Combellas, Frederic Kanoufi, Sandra Nunige Chemistry of Materials: A Publication of the American Chemistry Society . 2007 ,第15期

机译：卤化聚合物的表面改性。 10.乙烯基单体聚合的氧化还原催化诱导。乙烯基单体在聚四氟乙烯表面局部接枝共聚中的应用
3. GRAFT COPOLYMERS FOR BIOMEDICAL APPLICATIONS PREPARED BY FREE RADICAL POLYMERIZATION OF POLY(L-LACTIDE) MACROMONOMERS WITH VINYL AND ACRYLIC MONOMERS [J] . Eguiburu JL., Roman JS., Fernandezberridi MJ. Polymer: The International Journal for the Science and Technology of Polymers . 1996 ,第16期

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4. Ion Gels Prepared by In Situ Radical Polymerization of Vinyl Monomers in Room Temperature Ionic Liquids as Novel Highly Conductive Polymer Electrolytes [C] . Md. Abu Bin Hasan Susan, Akihiro Nada, Masayoshi Watanabe American Chemical Society . 2005

机译：通过在室温离子液体中原位自由基聚合制备的离子凝胶，如新型高导电聚合物电解质
5. I. Applications of iodine(III) reagents in the synthesis of nucleotides and amino acids. II. Synthesis and anionic polymerizations of vinyl monomers (Immune deficiency). [D] . Wang, Xiaohong. 1999

机译：I.碘（III）试剂在核苷酸和氨基酸合成中的应用。二。乙烯基单体的合成和阴离子聚合（免疫缺陷）。
6. Stepwise Thermo-Responsive Amino Acid-Derived Triblock Vinyl Polymers: ATRP Synthesis of Polymers Aggregation and Gelation Properties via Flower-Like Micelle Formation [O] . Nobuyuki Higashi, Sho Matsubara, Shin-nosuke Nishimura, 2018

机译：逐步热响应性氨基酸衍生的三嵌段乙烯基聚合物：ATRP合成聚合物聚集和通过像花胶束形成凝胶化性质。
7. Sulfur-Containing Polymers Prepared from Fatty Acid-Derived Monomers: Application of Atom-Economical Thiol-ene/Thiol-yne Click Reactions and Inverse Vulcanization Strategies [O] . Ashlyn D. Smith, Andrew G. Tennyson, Rhett C. Smith 2020

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Thermo-responsive polymer brushes on glass plate prepared from a new class of amino acid-derived vinyl monomers and their applications in cell-sheet engineering

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