Photovoltaic Counter Electrodes: An Alternative Approach to Extend Light Absorption Spectra and Enhance Performance of Dye‐Sensitized Solar Cells

摘要

Abstract If counter electrodes (CEs) could also contribute to light harvesting in dye‐sensitized solar cells (DSSCs), then the power conversion efficiency (PCE) of DSSCs would be further boosted without changing the device structure. Nearly monodispersed Ag 2 Se nanocrystals with a bandgap of 1.62?eV (～765?nm) were synthesized via a one‐pot process, and Ag 2 Se CEs were fabricated by using a spin‐coating and annealing process. Incident photon‐to‐current conversion efficiency and photocurrent spectra indicated that Ag 2 Se CEs can generate the electricity by harvesting more visible light, which could not be absorbed by dye‐sensitized photoanodes. Thus, compared to Pt CE (7.57?%), the DSSC based on Ag 2 Se CE exerted a higher PCE of 8.06?%. The development of photovoltaic CEs may offer an alternative way to promote the performance and competitiveness of DSSCs.